The following initial rate data are for the reaction of ICI with hydrogen: 2IC1 + H₂ → I₂ + 2HCl Experiment [IC10, M [H₂]o, M 0.198 0.141 0.396 0.141 0.198 0.281 0.396 0.281 1 2 3 4 Rate = Complete the rate law for this reaction in the box below. Use the form k[A]" [B]", where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. k = M-2 S Initial Rate, M s-¹ 0.00657 -1 0.0131 0.0261 0.0522

The following initial rate data are for the reaction of ICI with hydrogen: 2IC1 + H₂ → I₂ + 2HCl Experiment [IC10, M [H₂]o, M 0.198 0.141 0.396 0.141 0.198 0.281 0.396 0.281 1 2 3 4 Rate = Complete the rate law for this reaction in the box below. Use the form k[A]" [B]", where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. k = M-2 S Initial Rate, M s-¹ 0.00657 -1 0.0131 0.0261 0.0522

Chemistry for Engineering Students

3rd Edition

ISBN:9781285199023

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 11.52PAE

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In experiments on the decomposition of azomethane. CH3NHCH3(g)C2H6(g)+N2(g) the following data were obtained: Initial Concentration of Azomethane Initial Rate Exp. 1 1.13 102 M 2.8 106 M/s Exp. 2 2.26 102 M 5.6 106 M/s What is the rate law? What is the value of the rate constant?
Phenyl acetate, an ester, reacts with water according to the equation The data in the table were collected for this reaction at 5 C. (a) Plot the phenyl acetate concentration versus time, and describe the shape of the curve observed. (b) Calculate the rate of change of the phenyl acetate concentration during the period 15.0 seconds to 30.0 seconds and also during the period 75.0 seconds to 90.0 seconds. Why is one value smaller than the other?
What is the difference between average rate, initial rate, and instantaneous rate?
6. Phenyl acetate, an ester, reacts with water according to the equation The data in the table were collected for this reaction at 5°C. Time (s) [Phenyl acetate] (mol/L) 0 0.55 15.0 0.42 30.0 0.31 45.0 0.23 60.0 0.17 75.0 0.12 90.0 0.085 Plot the phenyl acetate concentration versus time, and describe the shape of the curve observed. Calculate the rate of change of the phenyl acetate concentration during the period 15.0 seconds to 30.0 seconds and also during the period 75.0 seconds to 90.0 seconds. Why is one value smaller than the other? What is the rate of change of the phenyl acetate concentration during the time period 60.0 seconds to 75.0 seconds? What is the instantaneous rate at 15.0 seconds?
Nitryl fluoride is an explosive compound that can be made by oxidizing nitrogen dioxide with fluorine: 2 NO2(g) + F2(g) → 2 NO2F(g) Several kinetics experiments, all done at the same temperature and involving formation of nitryl fluoride, are summarized in this table: Write the rate law for the reaction. Determine what the order of the reaction is with respect to each reactant and each product. Calculate the rate constant k and express it in appropriate units.
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The hydrolysis of the sugar sucrose to the sugars glucose and fructose, C12H22O11+H2OC6H12O6+C6H12O6 follows a first-order rate equation for the disappearance of sucrose: Rate =k[C12H22O11] (The products of the reaction, glucose and fructose, have the same molecular formulas but differ in the arrangement of the atoms in their molecules.) (a) In neutral solution, k=2.11011s1 at 27 C and 8.51011s1 at 37 C. Determine the activation energy, the frequency factor, and the rate constant for this equation at 47 C (assuming the kinetics remain consistent with the Arrhenius equation at this temperature). (b) When a solution of sucrose with an initial concentration of 0.150 M reaches equilibrium, the concentration of sucrose is 1.65107M . How long will it take the solution to reach equilibrium at 27 C in the absence of a catalyst? Because the concentration of sucrose at equilibrium is so low, assume that the reaction is irreversible. (c) Why does assuming that the reaction is irreversible simplify the calculation in pan (b)?
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Consider a hypothetical reaction between A and B: A + B products Use the following initial rate data to calculate the rate constant for this reaction. [A] (mol/L) [B] (mol/L) Initial Rate (mol/L s) 0.20 1.0 3.0 0.50 1.0 11.8 2.0 2.0 189.5
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One possible mechanism for the decomposition of nitryl chloride, NO2CI, is What is the overall reaction? What rate law would be derived from this mechanism? What effect does increasing the concentration of the product NO2 have on the reaction rate?
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