The following mechanism has been proposed for the reactionof NO with H2 to form N2O and H2O:NO(g) + NO(g)---->N2O2(g)N2O2(g) + H2(g)---->N2O(g) + H2O(g)(a) Show that the elementary reactions of the proposedmechanism add to provide a balanced equation for the reaction.(b) Write a rate law for each elementary reaction inthe mechanism. (c) Identify any intermediates in the mechanism.(d) The observed rate law is rate = k[NO]2[H2]. Ifthe proposed mechanism is correct, what can we concludeabout the relative speeds of the first and second reactions?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter13: Substitution
Section: Chapter Questions
Problem 8CTQ
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The following mechanism has been proposed for the reaction
of NO with H2 to form N2O and H2O:
NO(g) + NO(g)---->N2O2(g)
N2O2(g) + H2(g)---->N2O(g) + H2O(g)
(a) Show that the elementary reactions of the proposed
mechanism add to provide a balanced equation for the reaction.
(b) Write a rate law for each elementary reaction in
the mechanism. (c) Identify any intermediates in the mechanism.
(d) The observed rate law is rate = k[NO]2[H2]. If
the proposed mechanism is correct, what can we conclude
about the relative speeds of the first and second reactions?

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