The following two mass spectra represent 1-bromo-4-ethylbenzene and (1-bromoethyl)benzene, respectively. 100 - MS-IU-9451 Spectrum 1 80 - 40 20 - 25 50 75 100 125 150 175 m/z 100 - Spectrum 2 MS-NU-8350 80 - 60 - 40 - 20 - 20 40 60 80 100 120 140 160 180 200 m/z 1. Assign each spectrum to one compound 2. Justify your assignment by assigning relevant signals in each spectrum. 3. Explain how you could determine which spectrum belongs to which compound. Relative Intensity Relative Intensity

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter12: Structure Determination: Mass Spectrometry And Infrared Spectroscopy
Section12.SE: Something Extra
Problem 49AP: The infrared spectrum of the compound with the mass spectrum shown below has a medium-intensity peak...
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The following two mass spectra represent 1-bromo-4-ethylbenzene and (1-bromoethyl)benzene,
respectively.
100 -
MS-IU-9451
Spectrum 1
80 -
60
40
20 -
25
50
75
100
125
150
175
m/z
100 -
MS-NU-8350
Spectrum 2
80 -
60
20-
20
40
60
80
100
120
140
160
180
200
m/z
1. Assign each spectrum to one compound
2. Justify your assignment by assigning relevant signals in each spectrum.
3. Explain how you could determine which spectrum belongs to which compound.
Relative Intensity
Relative Intensity
Transcribed Image Text:The following two mass spectra represent 1-bromo-4-ethylbenzene and (1-bromoethyl)benzene, respectively. 100 - MS-IU-9451 Spectrum 1 80 - 60 40 20 - 25 50 75 100 125 150 175 m/z 100 - MS-NU-8350 Spectrum 2 80 - 60 20- 20 40 60 80 100 120 140 160 180 200 m/z 1. Assign each spectrum to one compound 2. Justify your assignment by assigning relevant signals in each spectrum. 3. Explain how you could determine which spectrum belongs to which compound. Relative Intensity Relative Intensity
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