Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter20: Kinetics
Section: Chapter Questions
Problem 20.42E
Related questions
Question
The half life of a first order reaction is given as 15.6 days. How long will it take to decompose to 10% ?
Expert Solution
Step 1 Rate constant and t1/2 relation
1) First order rate constant
K1 = 2.303/t log(a)/(a-x)
2) K1 and t1/2 relation
K1 = 0.693/ t1/2
Let us take
Intial concentration= a = 100
Consumed to 10% that means
90% completed and 10 % remaining
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