The molar extinction coefficient of B (MW = 180) is 4x10 lit mol' cm'. One liter solution of C which contains 0.1358 g pharmaceutical preparation of B, shows an absorbance of 0.411 in a 1 cm quartz cell. The percentage (w/w) of B in the pharmaceutical preparation is: (a) 10,20 (b) 14.60 (c) 20.40 (d) 29. 12
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- The following data were obtained on the initial rates of reaction of a d-metal complex in aqueous solution. For the experiments a. [Y] = 2.7 mmol/dm3, and for experiments b. [Y] = 6.1 mmol/dm3 Conc. complex/(mmol dm-3) 8.01 9.22 12.11 Exp. a. v/ (mol dm-3 s-1) 125 144 190 Exp. b. v/ (mol dm-3 s-1) 640 730 960 (a) What is the order of reaction with respect to the complex AND the reactant Y. Choose one. (b) use the data above to calculate the rate constant. k = ________ (mol/L/s, s-1, L/mol/s, or L2/mol2/s). 3 s.f. normal format.The following data were obtained on the initial rates of reaction of a d-metal complex in aqueous solution. For the experiments a. [Y] = 2.7 mmol/dm3, and for experiments b. [Y] = 6.1 mmol/dm3 Conc. complex/(mmol dm-3) 8.01 9.22 12.11 Exp. a. v/ (mol dm-3 s-1) 125 144 190 Exp. b. v/ (mol dm-3 s-1) 640 730 960 (a) What is the order of reaction with respect to the complex AND the reactant Y. (b) use the data above to calculate the rate constant. k = ________ (mol/L/s, s-1, L/mol/s, or L2/mol2/s). 3 s.f. normal format.The following data were obtained on the initial rates of reaction of a d-metal complex in aqueous solution. For the experiments a. [Y] = 2.7 mmol/dm3, and for experiments b. [Y] = 6.1 mmol/dm3 Conc. complex/(mmol dm-3) 8.01 9.22 12.11 Exp. a. v/ (mol dm-3 s-1) 125 144 190 Exp. b. v/ (mol dm-3 s-1) 640 730 960 (a) What is the order of reaction with respect to the complex AND the reactant Y. Choose one.
- The following data were obtained on the initial rates of reaction of a d-metal complex in aqueous solution. For the experiments a. [Y] = 2.7 mmol/dm3, and for experiments b. [Y] = 6.1 mmol/dm3 Conc. complex/(mmol dm-3) 8.01 9.22 12.11 Exp. a. v/ (mol dm-3 s-1) 125 144 190 Exp. b. v/ (mol dm-3 s-1) 640 730 960 b) use the data above to calculate the rate constant. k = ________ (mol/L/s, s-1, L/mol/s, or L2/mol2/s). 3 s.f. normal format.The kinetics of hydrolysis of acetylsalicylic acid (aspirin) under certain conditions of temperature, pH, type of buffer and strength ionic, can be followed by multicomponent spectrophotometry. When performing a calculation of optical constants, the following data were obtained: Solution C. mg/100 mL A in λ (276nm) A in λ (290nm) Ac. acetylsalicylic ( AAS) 0.202 0.102 0.031 Ac. salicylic (AS) 0.198 0.158 0.101 Reaction: AAS + H2O → AS + CH3COOH In a kinetic study, after a certain time, 1 mL of the solution was taken from the reactor and diluted to 10 mL with water. distilled. Then when proceeding to the spectrophotometric measurement, the last solution presented the absorbances of 0.244 and 0.102 for the lengths of 276 and 290 nm respectively. What are the concentrations of ASA and AS in mg/L, at that instant in the reactor? Note: Acetic acid does not absorb at either wavelength.What is the pathlength in centimeters when the molar absorptivity for a given absorbing species is 1.32 ¥ 103 L mol-1 cm-1, the concentration is 0.000923 M, and the absorbance is 0.493?
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