The order of the reaction, ? → products, is being determined through the half-life method. Two setups at the same temperatures but different starting concentrations of A were investigated. For the first run, the initial concentration of A was 0.78 M and the halflife was determined to be 45 minutes. In the second run, the initial concentration of A was 1.32 M. Determine the following : a. If the reaction is 1st order, what should be the half-life of the second run in minutes?

Chemistry: An Atoms First Approach
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ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter11: Chemical Kinetics
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Problem 6RQ: Derive expressions for the half-life of zero-, first-, and second-order reactions using the...
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Half-life of a reaction

The order of the reaction, ? → products, is being determined through the half-life method. Two setups at the same temperatures but different starting concentrations of A were investigated. For the first run, the initial concentration of A was 0.78 M and the halflife was determined to be 45 minutes. In the second run, the initial concentration of A was 1.32 M.

Determine the following :

a. If the reaction is 1st order, what should be the half-life of the second run in minutes?

b. If the reaction is 2nd order, what should be the half-life of the second run in minutes?

c. If the reaction is 0th order, determine the concentration of A in the second run after 152.3 minutes.

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