The pressures deep within the Earth are much greater than those on the surface, and to make use of thermochemical data in geochemical assessments you need to take the differences into account. (a) Given that the enthalpy of combustion of graphite is -393.5 kJ mol-1 and that of diamond is -395.41 kJ mol-1, calculate the standard enthalpy of the C(s, graphite) → C(s, diamond) transition. (b) The densities of graphite and diamond are 2.250 g cm-3 and 3.510 g cm-3 , respectively. Calculate the internal energy of the transition when the sample is under a pressure of 150 kbar.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
The pressures deep within the Earth are much greater than those on the surface, and to make use of thermochemical data in geochemical assessments you need to take the differences into account. (a) Given that the enthalpy of combustion of graphite is -393.5 kJ mol-1 and that of diamond is -395.41 kJ mol-1, calculate the standard enthalpy of the C(s, graphite) → C(s, diamond) transition. (b) The densities of graphite and diamond are 2.250 g cm-3 and 3.510 g cm-3 , respectively. Calculate the internal energy of the transition when the sample is under a pressure of 150 kbar.
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