The rate law for the oxidation reaction 2CO(g) + O2(g) → 2CO2(g) assuming that the reaction occurs by the Langmuir -Hinshelwood mechanism. The over-all rate law for this mechanism is Rate = k3θCOθO2 ΘO2 = (KO2 [O2])1/2 and ΘCO = KCO [CO] --------------------------------- --------------------------------- 1+ (KO2[O2])1/2 + KCO[CO] 1+ (KO2[O2])1/2 + KCO[
The rate law for the oxidation reaction 2CO(g) + O2(g) → 2CO2(g) assuming that the reaction occurs by the Langmuir -Hinshelwood mechanism. The over-all rate law for this mechanism is Rate = k3θCOθO2 ΘO2 = (KO2 [O2])1/2 and ΘCO = KCO [CO] --------------------------------- --------------------------------- 1+ (KO2[O2])1/2 + KCO[CO] 1+ (KO2[O2])1/2 + KCO[
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter20: Kinetics
Section: Chapter Questions
Problem 20.90E
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The rate law for the oxidation reaction 2CO(g) + O2(g) → 2CO2(g) assuming that the reaction occurs by the Langmuir -Hinshelwood mechanism.
The over-all rate law for this mechanism is Rate = k3θCOθO2
ΘO2 = (KO2 [O2])1/2 and ΘCO = KCO [CO]
--------------------------------- ---------------------------------
1+ (KO2[O2])1/2 + KCO[CO] 1+ (KO2[O2])1/2 + KCO[CO]
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