The rate of the following reaction in aqueous solution is monitored by measuring the number of moles of Hg₂Cl2 that precipitate per liter per minute. The data obtained are listed in the table. 2HgCl2 (aq) + C₂04²¯ (aq) • Experiment (1) (ii) (iii) (iv) 2 3 4 [HgCl₂] (M) 0.1050 0.1050 0.0525 0.0525 2C1 (aq) + 2CO2 (aq) + Hg₂Cl2 (s) [C₂04²] (M) 0.15 0.30 0.30 0.15 Initial rate (mol L-¹ min-¹) 1.8 x 10-5 7.1 x 10-5 3.5 x 10-5 8.9 x 10-6 Determine the order of reaction with respect to HgCl2, with respect to C₂04²- and overall. What is the value of the rate constant, k? What would be the initial rate of reaction if [HgCl₂] = 0.074 M and [C₂04²-] = 0.29 M? Are all four experiments necessary to answer parts (1) - (iii)? Explain.
The rate of the following reaction in aqueous solution is monitored by measuring the number of moles of Hg₂Cl2 that precipitate per liter per minute. The data obtained are listed in the table. 2HgCl2 (aq) + C₂04²¯ (aq) • Experiment (1) (ii) (iii) (iv) 2 3 4 [HgCl₂] (M) 0.1050 0.1050 0.0525 0.0525 2C1 (aq) + 2CO2 (aq) + Hg₂Cl2 (s) [C₂04²] (M) 0.15 0.30 0.30 0.15 Initial rate (mol L-¹ min-¹) 1.8 x 10-5 7.1 x 10-5 3.5 x 10-5 8.9 x 10-6 Determine the order of reaction with respect to HgCl2, with respect to C₂04²- and overall. What is the value of the rate constant, k? What would be the initial rate of reaction if [HgCl₂] = 0.074 M and [C₂04²-] = 0.29 M? Are all four experiments necessary to answer parts (1) - (iii)? Explain.
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter7: Reaction Rates And Chemical Equilibrium
Section: Chapter Questions
Problem 7.12P: 7-12 Two kinds of gas molecules are reacted at a set temperature. The gases are blown into the...
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