The reaction 3ClO-(aq) → ClO3-(aq) + 2Cl-(aq) has been proposed to occur by the following mechanism: ClO-(aq) + ClO-( aq)→ ClO2-(aq) + Cl-( aq) (slow) ClO2-(aq) + ClO-(aq) → ClO3-(aq) + Cl-(aq) (fast) Which rate law is consistent with this mechanism?
The reaction 3ClO-(aq) → ClO3-(aq) + 2Cl-(aq) has been proposed to occur by the following mechanism: ClO-(aq) + ClO-( aq)→ ClO2-(aq) + Cl-( aq) (slow) ClO2-(aq) + ClO-(aq) → ClO3-(aq) + Cl-(aq) (fast) Which rate law is consistent with this mechanism?
Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 8RQ
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The reaction
3ClO-(aq) → ClO3-(aq) + 2Cl-(aq)
has been proposed to occur by the following mechanism:
ClO-(aq) + ClO-( aq)→ ClO2-(aq) + Cl-( aq) (slow)
ClO2-(aq) + ClO-(aq) → ClO3-(aq) + Cl-(aq) (fast)
Which rate law is consistent with this mechanism?
a.
rate = k [Cl-][ClO-]2
b.
rate = k [ClO-]2
c.
rate = k [ClO3-]3
d.
rate = k [ClO2-][ClO-]
e.
rate = k[ClO-]
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