The reaction between bromate ions and bromide ions in acidic aqueous solution is given by the following equation:BrO3- (aq) + 5Br- (aq) + 6H+ (aq) --> 3Br2 (l) + 3H2O (l)The experimental results are given below.ExperimentInitial [BrO3-]Initial [Br-]Initial [H+]Initial Rate (M s-1)10.100.100.108.0 x 10-420.200.100.101.6 x 10-330.200.200.103.2 x 10-340.100.100.203.2 x 10-3Using these data, determine the orders for all reactants, the overall reaction order, and the value of the rate constant.

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Answered: The reaction between bromate ions and…

Appl Of Ms Excel In Analytical Chemistry

2nd Edition

ISBN:9781285686691

Author:Crouch

Publisher:Crouch

Chapter13: Kinetic Methods

Section: Chapter Questions

Problem 1P

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The reaction between bromate ions and bromide ions in acidic aqueous solution is given by the following equation:

BrO^3-(aq) + 5Br^- (aq) + 6H⁺ (aq) --> 3Br₂ (l) + 3H₂O (l)

The experimental results are given below.

Experiment	Initial [BrO^3-]	Initial [Br^-]	Initial [H⁺]	Initial Rate (M s^-1)
1	0.10	0.10	0.10	8.0 x 10^-4
2	0.20	0.10	0.10	1.6 x 10^-3
3	0.20	0.20	0.10	3.2 x 10^-3
4	0.10	0.10	0.20	3.2 x 10^-3

Using these data, determine the orders for all reactants, the overall reaction order, and the value of the rate constant.

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