Answered: The reaction between peroxodisulphate…

The reaction between peroxodisulphate (VI) ions, S2O82- and iodide ions, I- can be catalyzed by iron(III) ions, Fe3+. Suggest a mechanism for the catalytic reaction.

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter21: Benzene And The Concept Of Aromaticity

Section: Chapter Questions

Problem 21.43P: Following is an equation for iodination of toluene. This reaction does not take place. All that...

See similar textbooks

Related questions

Q: 9) Product formation of the following reaction A + 2B → AB, was experimentally determined to have a…

Q: ). Suggest mechanisms that account for the outcome of the following reactions: а. Si(CH3)3 1) Br2,…

Q: Compounds like Sodium acetate (CH3COONa); Pyridine ; Boron trifluoride (BF3), and Sulfuric acid…

A: Aspirin is acetylsalicylic acid. The molecular formula of aspirin is C9H8O4. It is an aromatic…

Q: For the reaction shown, the rate of reaction when X=Cl is about the same as that when X=Br. Based on…

A: The given reaction is represented as follows:

Q: . A key step in the formation of sulfuric acid from dissolved SO2 in acid precipitation is the…

A: N2+3 H2 ⇌ 2 NH3HSO3-(aq) + H2O2(aq) k1⇌k-1 SO2OOH-(aq)+H2O(l)SO2OOH-(aq)+ H3O+(aq) →k2 HSO1-(aq) +…

Q: An elemental step in a reaction can be written as D + E → products. The molecularity of this step is…

Q: You have studied the gas-phase oxidation of HBr by O2:4 HBr(g) + O2(g) -->2 H2O(g) + 2 Br2(g) You…

A: For the given overall reaction: 4 HBr(g) + O2(g) -->2 H2O(g) + 2 Br2(g) The reaction is first…

Q: Et Br NH₂ Et Et M IZ

Q: Predict the products and mechanisms of the following reactions. When more than oneproduct or…

A: The reaction between isobutyl chloride and AgNO3 in presence of ethanol and water has been described…

Q: 1) Mg. 6ther HBr B 2) puis H,0

A: Markovnikov addition of alkene.

Q: C,H¬Br + OH¯→ C,H¬OH + NaBr The rate equation for the hydrolysis of C3H,Br with sodium hydroxide is:…

Q: What would be the missing steps and intermediates for the following reaction?

A: We have to complete the steps of conversion of cyclohexane to adipic acid.

Q: In a typical laboratory setting, a reaction is carried out in a ventilated hood with air circulation…

A: Rate of a reaction depends on temperature. As the temperature increases, the rate also increases.…

Q: 2. (a) The solvolysis reaction of compound 2A in acetic acid generated two major products 2B and 2C.…

A: The above reaction is the substitution reaction. The Tosyl group is a good leaving group and the…

Q: By what mechanism is the following reaction likely to occur? Br NaOMe O E1 O E2 O SN1 O SN2

A: Alkyl halide reacts with sodium methoxide to form alkene, by the biomolecular elimination reaction.

Q: In unpolluted air at 300 K, the hydroxyl radical OH reacts with CO with a bimolecular rate constant…

A: It is given that hydroxyl radical OH reacts with CO with a bimolecular rate constant of 1.6 × 1011…

Q: The aquation of CrCl2(OH2)4 + to CrCl(OH2)5 2+ is catalyzed by Cr(OH2)6 2+. Write a reasonable…

A: [Cr(H2O)]3+ helps in the catalysis of the aquation of [Cr(H2O)4Cl2]+

Q: d) During the reaction between 3, 3-dimethylbutene (W) and HBr, intermediate species and Y are…

A: The above reaction is addition reaction of HBr on alkene.

Q: 1) Hg(OAc)2, H20 2) NABH4 1. Mg 2. H2CO Br 3. H3O*

A: 1) Electrophilic addition is a reaction between an electrophile and nucleophile, adding to double…

Q: The reaction between peroxodisulphate (VI) ions, S2O82- and iodide ions, I- can be catalyzed by…

A: Ions of peroxodisulfate (VI) ions is reacted with iodide ions to produce sulfate (VI) ions and…

Q: Shown below is the structure of eicosapentaenoic acid (EPA) OH One of the autooxidation products of…

A: Autooxidation is slow oxidation process of any organic compound, with the help of atmospheric…

Q: A key step in the formation of sulfuric acid from dissolved SO, in acid precipitation is the…

Q: Describe the following :(i) Tyndall effect(ii) Shape-selective catalysis

A: Tyndall effect is one of the property exhibited by colloidal solution. This effect was observed…

Q: Define Characteristics of the E2 Mechanism ?

Q: Suppose the following exchange of water reactions were carried out by an associative mechanism…

Q: MTBE (methyl tert-butyl ether) has been used as a petroleum additive to increase octane rating,…

Q: Organic chemistry:Describe the mechanism for preparation of methyl salicylate from salicylic acid (…

Q: (b) Comment on the molecularity, and order of the reaction, hydrolysis of sucrose to glucose and…

A: Recall the given reaction, C12H22O11 + H2O → C6H12O6 + C6H12O6Here we…

Q: Br NaN3, DMF 75 °C Br ISI KSCH3 CI Aseton

Q: 1. The rate constants for the formation of Co(NH 3 )5 X]^ 2+ from [Co(NH 3 )5 H 2 O]^ 3+ for X=Cl^…

Q: 8.0° NaOH Ethanol

A: Given reaction is aldol condensation reaction.

Q: Br H20

Q: Write integrated rate laws for zero-order, first-order, and secondorder reactions of the form…

Q: Bromomethylcycloheptane has been prepared in 92% yield by the reaction that it shows. Write a…

A: Alcohol on reaction with Hydrogen Bromide(HBr) in the presence of water yields an alkyl halide.

Q: Define the Mechanisms of Elimination ?

Q: 1-Suggest a mechanism by which the ozone, O3 is being destructed by the presence of oxygen molecule,…

A: 1. The decomposition of ozone photo chemically is shown in the steps below : The ozone is…

Q: The second-order rate constants for the reaction of oxygen atoms with aromatic hydrocarbons have…

A: Given: k1=1.44×107 dm3/mol s (1 L = 1 dm3)=1.44×107 L/mol s Initial temperature (T1) =300 K Final…

Q: H* 2. H2O

A: This is the hydrolysis of alkene . So on hydrolysis , the given reactant will give an alcohol .

Q: MCPBA 1. NaSH 2. H20

A: In organic chemistry, inter conversion of organic molecule takes place from one form to another form…

Q: Consider this scenario and answer the following questions: Chlorine atoms resulting from…

A: A catalyst is a substance that helps in accelerating a chemical reaction, without itself being…

Q: OH 1. 2 mol PhMgBr OCH, 2. H;O* 1) Hg(OAc)2, H20 2) NaBH4 1. Mg Br 2. H2CO 3. H;O*

A: The basic organic reactions are : 1. Addition reactions, 2.Elimination reactions, 3.Rearrangement…

Q: ОН Н-Br PR3 step 1 Br R3P step 2

Q: 5- Does SN2 occur in one step while SN1 occurs in three steps?

A: Nucleophilic substitution reaction: Nucleophilic substitution is a class of chemical reaction in…

Q: Which of the following scheme is the first step in the following Grignard reaction? + I. BrMg I.…

A: Ketone behaves as a Elctrophile while grignard reagent as nucleophile therfore nucleophile attack on…

Q: The reaction between peroxodisulphate (VI) ions, S2O8²- and iodide ions, I- can be catalyzed by…

A: The reaction which occurs in presence of catalyst is known as catalyzed reaction while the reaction…

Q: Please use the values in the resources listed below instead of the textbook values. The rate of the…

Q: Cleavage of C2H6 to produce two CH3· radicals is a gas-phase reaction that occurs at 700 °C. This…

A: Given: k=5.46×10-4 s-1temperature=700oC To find: Time taken to go to 15% completion

Q: 10% PdCl,(PPh,), CSH,Br + CH,,02 20% PPh, OEt D E F NEt, Figure 4 (ii) Name the reaction occurring…

Question

The reaction between peroxodisulphate (VI) ions, S₂O₈^2- and iodide ions, I- can be catalyzed by iron(III) ions, Fe³⁺.

Suggest a mechanism for the catalytic reaction.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Data given:

VIEW

Mechanism of the catalytic reaction:

VIEW

Mechanism continued..

VIEW

Step by step

Solved in 3 steps

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

The reaction between peroxodisulphate (VI) ions, S2O82- and iodide ions, I- can be catalyzed by iron(III) ions, Fe3+. (a)Suggest a mechanism for the catalytic reaction.(b)Sketch an energy profile diagram for the catalyzed and uncatalyzed reactions.
Consider the reaction of [V(H2O)6]2+ with [Co(NH3)5X]2+ in acidic aqueous solution (X = halide or NCS–) producing [V(H2O)5X]2+ and [Co(H2O)6]2+. Suggest the mechanism, considering that the rate constant is very similar for X = Cl, Br, I. Characterize in few words individual steps. Explain the nature of the rate-determining step in terms of the [V(H2O)6]2+ electron configuration.
If 0.70 g of FeCl3 is used to iodinate 8.42 g of benzene with sufficient ICl, what is the average number of reactions that each FeCl3 molecule must catalyze?
Following is an equation for iodination of toluene. This reaction does not take place. All that happens under experimental conditions for the formation of radicals is initiation to form iodine radicals, I , followed by termination to reform I2. How do you account for these observations?
[Rh(PPh3)3Cl] is a precatalyst that can be activated by dissociation of a phosphine ligand to form an active catalyst, B, which is used in the hydrogenation of alkenes. The active catalyst can then undergo oxidative addition in the presence of H2 to form complex C. Propene coordinates to C to form complex D, which then undergoes a 1,2- insertion step to form E. Reductive elimination of propane from E regenerates the active catalyst B. Draw complexes B – E and hence provide a full catalytic cycle, including the activation step, for the hydrogenation of propene
We have a hydrocarbon, C16H26. The compound has two triple bonds and the acids produced by ozonolysis are CH3(CH2)4CO2H and H2OCCH2CO2H. What is a likely structure for this hydrocarbon?
Outline the possible reaction pathways with proper mechanism for the formation ofNylon 6 from Benzene molecule.
The deuterium kinetic isotope effect for the halogenation of an alkane is defined in the following equation, where X. = Cl. or Br. Predict whether chlorination or bromination would have a greater deuterium kinetic isotope effect.
If the Arrhenius constant is 2.4x106 and the activation energy is 56.7 kJ/mol for the complex whose acid hydrolysis kinetics you are examining, what is the rate constant of the reaction at 65 ºC?
3. The reaction of bromine with 3-hexanone produces two isomeric products of formula C6H11BrO. Give the mechanism for obtaining the two isomers.
In the acylation of ferrocene what purpose does phosphoric acid serve as. Produce a mechanism for the reaction.
Briefly outline the Woodward-Hoffman description and explain how they can be used to predict if a pericyclic reaction will occur thermally or photochemically.