The reaction CO + Cl2 COCl2 was studied by the initial rate method and the following data were obtained: Initial Rate [CO], (M) [Cl₂], (M) (mol/Lxs) 1.00 × 10-2 1.00 x 10-2 6.60 × 103 3.00 × 10-2 1.00 × 10-2 1.98 x 104 1.00 * 10-2 4.00 × 10-2 1.06 x 105 The rate law is: O rate= K[Cl2] rate= K[CO][Cl₂] O rate= O rate = K[CO][C1₂]² O rate= = K[CO]²[C1₂] = K[CO][Cl₂]1/2

Chemistry: The Molecular Science
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ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.5: Temperature And Reaction Rate: The Arrhenius Equation
Problem 11.9E: The frequency factor A is 6.31 108 L mol1 s1 and the activation energy is 10. kJ/mol for the...
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The reaction CO + Cl₂ → COCl2 was studied by the initial rate method and the following data were obtained:
Initial Rate
[Cl₂], (M)
(mol/Lxs)
[CO], (M)
1.00 × 10-2
1.00 × 10-2
6.60 × 103
3.00 x 10-2
1.00 × 10-2
1.98 x 104
1.00 × 10-2
4.00 x 10-2
1.06 x 105
The rate law is:
O rate= K[Cl2]
O rate = k[CO][Cl2]
rate= = K[CO][C1₂]1/2
O rate = K[CO][C1₂]²
rate =
K[CO]²[C1₂]
Transcribed Image Text:The reaction CO + Cl₂ → COCl2 was studied by the initial rate method and the following data were obtained: Initial Rate [Cl₂], (M) (mol/Lxs) [CO], (M) 1.00 × 10-2 1.00 × 10-2 6.60 × 103 3.00 x 10-2 1.00 × 10-2 1.98 x 104 1.00 × 10-2 4.00 x 10-2 1.06 x 105 The rate law is: O rate= K[Cl2] O rate = k[CO][Cl2] rate= = K[CO][C1₂]1/2 O rate = K[CO][C1₂]² rate = K[CO]²[C1₂]
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