The reaction of CO with Cl2 gives phosgene (COCl2), a nerve gas that was used in World War I. Use the mechanism shown here to complete the following exercises:Cl2(g) ⇌ 2Cl(g) (fast, k1 represents the forward rate constant, k−1 the reverse rate constant)CO(g) + Cl(g) ⟶ COCl(g) (slow, k2 the rate constant)COCl(g) + Cl(g) ⟶ COCl2(g) (fast, k3 the rate constant)(a) Write the overall reaction.(b) Identify all intermediates.(c) Write the rate law for each elementary reaction.(d) Write the overall rate law expression.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter12: Chemical Equilibrium
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The reaction of CO with Cl2 gives phosgene (COCl2), a nerve gas that was used in World War I. Use the mechanism shown here to complete the following exercises:
Cl2(g) ⇌ 2Cl(g) (fast, k1 represents the forward rate constant, k−1 the reverse rate constant)
CO(g) + Cl(g) ⟶ COCl(g) (slow, k2 the rate constant)
COCl(g) + Cl(g) ⟶ COCl2(g) (fast, k3 the rate constant)
(a) Write the overall reaction.
(b) Identify all intermediates.
(c) Write the rate law for each elementary reaction.
(d) Write the overall rate law expression.

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