Write the overall reaction and the rate laws that corre- spond to the following reaction mechanisms. Be sure to eliminate intermediates from the answers. (a) 2 A + B = D (fast equilibrium) k-s k2 D + B → E + F (slow) ks F , G (fast) (b) A + B= C (fast equilibrium) k2 C+D 2 F k-2 (fast equilibrium) k F , G (slow)
Write the overall reaction and the rate laws that corre- spond to the following reaction mechanisms. Be sure to eliminate intermediates from the answers. (a) 2 A + B = D (fast equilibrium) k-s k2 D + B → E + F (slow) ks F , G (fast) (b) A + B= C (fast equilibrium) k2 C+D 2 F k-2 (fast equilibrium) k F , G (slow)
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter18: Chemical Kinetics
Section: Chapter Questions
Problem 22P
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