Answered: the rotational constant for 1H35Cl is…

Science

Chemistry

the rotational constant for 1H35Cl is 10.6 cm-1 . What are the degeneracies, g, of the J=2, and J=3 rotational states?

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter18: More Statistical Thermodynamics

Section: Chapter Questions

Problem 18.32E

See similar textbooks

Related questions

Q: It took 9.1 minutes for3.0 L helium to effuse through a porous barrier. How long will it take for…

A: According to Graham's Law of effusion, Rate of effusion ARate of effusion B = Molar mass of BMolar…

Q: If the entropy of a reactions is -264.54 J/ mole K and the enthalpy of the reaction is 117.63…

Q: The numerical value of the term e -kt at a time equal to 3 half lives of a drug will always be equal…

Q: Write a complete equation for the reaction of two methanol molecules with propanal.

A: The given question describes the reaction between aldehyde and two molecules of methanol to give…

Q: Electron capture transforms Be into what nuclide? Question 3 options: a) Li b) Li c)…

Q: 2. Draw a galvanic cell containing Zn/Zn²+ (0.25 M) couple and Ag/AgCl(3.5M KCl) electrode connected…

A: Galvanic cell is the cell which convert chemical energy into electrical energy. Two electrods, anode…

Q: In an aqueous solution at 25 °C, if [H₂O*] = 2.4 × 104 M, then [OH-] is:

Q: Fill in the potential double replacement products for each reaction shown below. Then for any that…

A: A replacement reaction is the reaction where one group or functional group is replaced by the other…

Q: 4. Give an example of the following (where CN is coordination number) and include the point group:…

Q: (COCI)2 DMF OH Hexane (CH;CH,),NH CI Hexane

A: Oxalyl chloride is also used for conversion of carboxylic acid to acid chloride.

Q: decay series of uranium- 238 includes 3 different isotopes of polonium. Which of these isotopes you…

A: Uranium-238 is a radioactive element that undergoes a complex decay series, eventually transforming…

Q: Calculate the number of grams of metal M produced in 1.815 hour by the electrolysis if the…

A: To calculate the number of grams of metal M produced by electrolysis, we need to use Faraday's laws…

Q: Consider a reaction occurring in a battery. If E° = 0.867 V and there are 3 number of electrons…

A: E°=0.867 Vn= 3

Q: Consider the following cell notation and use a Table of Standard Electrode Potentials to calculate…

A: Nernst equation gives the relationship between the variation of concentration of electrolyte and…

Q: Consider the [CoBr214]4 complex from the standpoint of the crystal field theory. Sketch the d…

Q: Consider the reaction CO(g) + Cl₂(g) COCI₂(g) Using the standard thermodynamic data in the tables…

Q: The accumulation of ketone bodies in the blood results in which of the following? A. a decrease in…

Q: Give a pair of atoms (not a generic description, but two specific atoms) that fit the following…

A: In short, polar, nonpolar, and ionic bonds can be defined as follows: Polar covalent bonds: These…

Q: Li is an incomplete answer. Please choose from one of the anser options provided

A: We will discuss about the electron capture by B47e The mass number does not fhange by an electron…

Q: To help derive the relationships shown in the various gas laws, you will be using an interactive…

Q: Suppose the galvanic cell sketched below is powered by the following reaction: Fe(s)+3 AgNO3(aq)…

Q: For the reaction 2NO(g) + 2H₂(g) N₂(g) + 2H₂O(l) AH = -752.2 kJ and AS° = -351.6 J/K The maximum…

A: Answer:- This question is answered by using the simple concept of calculation of maximum work during…

Q: 2) Consider the reaction below: -9 -4 SnCl2(aq) + HgCl2 (aq) → Hgm + Snc Oxidized 2+4 shat A) Write…

Q: What is ECELL if [Pb²+] = 10.0 M and [Ag] = 1.0 × 106 M? +1.31 V +0.925 V +0,541 V Question 4

Q: 12.a. Consider AlCl3. What is the hybridization of Al in AlCl3? 12.b. Draw the electron…

A: Aluminum chloride (AlCl3) is an ionic compound that exists as a crystalline solid at room…

Q: A buffer solution is prepared by combining 0.898 moles of formic acid and 0.733 moles of sodium…

A: The buffer solution is prepared by mixing with 0.898 moles of formic acid and 0.733 moles of sodium…

Q: Draw open structures of these coordination compounds. Sodium tetracyanonicalate(II) ,…

Q: From the reaction 2 C12H22011 (g) + 24 O2 (g) -->24 CO2 (g) + 22 H₂O (1) Calculate the number of…

A: Since you have posted multiple questions, we will provide the solution only to the first question as…

Q: 3. Draw the voltaic cell (labeling the anode, cathode, and salt bridge) for the reaction between…

Q: In the first step of ß-Oxidation, R H H -S-CoA Acyl COA In the third step of B-Oxidation, ОНН О ||…

A: An oxidizing agent is species in Redox reaction which accepts or gains electrons from reducing…

Q: b) Give the systematic name for each of the following complexes: (i) (ii) [Fe(en)2Cl2][BF4] (iii)…

A: Here we have to give the systematic name of the above compounds-

Q: Calculate the emf of the following concentration cell: Mg(s) | Mg2+(0.25 M) || Mg2+(0.79 M) | Mg(s)

A: The concentration cell contains the same material on both half cell with different concentration of…

Q: Find the hydroxide-ion concentration for a solution with pH = 6.00

A: pH = 6.00 [OH-] = ?

Q: How to make 1% strach indicator in 250 ml water

A: Volume of water = volume of solution = 250 ml We have to make 1% of starch solution i.e starch…

Q: 6) Cobalt-60 is a radioisotope used as a source of ionizing radiation in cancer treatment (The…

A: A 1000 mg sample of radioactive cobalt-60. Half life = 5 years Time (t) = 10 years

Q: In a chlorous acid (HClO2) buffer, chlorous acid will neutralize added __________. water hydroxide…

A: definition of a buffer is a solution with reserve acidity or alkalinity that resists pH change when…

Q: what is the chemical equation?

Q: The fuel value of hamburger is approximately 3.6 kcal/g. If a man cats 0.55 pounds of hamburger for…

A: The fuel value of hamburger = 3.6 kcal/g fuel value = 0.55 pounds The heat of vaporization of water…

Q: onsider the reaction: H₂CO(g) + O₂(g) → CO₂(g) + H₂O(1) Using standard absolute entropies at 298 K,…

Q: C. time 2. Which statement is incorrect? a. The vapor pressure is the pressure that results from…

A: Statement b, c and d are correct statements.

Q: Predict the products of the following reaction: NaOH

A: In the question, there is a reaction between acid amide and sodium hydroxide to form corresponding…

Q: annotate

A: Infrared spectroscopy deals with the analysis of various peaks in the spectrum that represent the…

Q: HNO3 H₂SO4

Q: 5. What is the on for the reaction shown below? CO(g) + 3 H2(g) → CH4(g) + H2O(g)

Q: 42. Consider the carbohydrates below and choose the statement that is true. CHO -OH H- HO-H H- HO-…

A: Enantiomers are the structures that are nonsuperimposable mirror images of each other. Diastereomers…

Q: The following information is given for ethanol, C₂H5OH, at 1 atm: AHvap (78.4 °C) = 38.6 kJ/mol…

A: Answer: In vaporization process matter has been converted form its liquid state to vapor state by…

Q: Electronegativity is defined as the relative ability of an atom in a molecule to attract shared…

A: Electronegativity is a measure of an atom's ability to attract electrons towards itself when it is…

Q: From the Fischer projection, determine the designation of this monosaccharide. A) D B) L C) D, L HO…

Q: following information is given for ethanol at 1 atm: The To = 78.40°C Tm = -114.50°C Specific heat…

A: Answer: It is a 3 step process: 1. Heating of liquid ethanol up to its boiling point 2. Vaporization…

Q: Identify peaks in the 1H spectrum that correspond to the t-butyl group, the phenyl groups, and the…

A: The number of peaks, present in a NMR spectrum, gives the number of different types of hydrogen…

Concept explainers

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.

Question

the rotational constant for ¹H³⁵Cl is 10.6 cm^-1 . What are the degeneracies, g, of the J=2, and J=3 rotational states?

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1: Given data

VIEW

Step 2: Calculate the degeneracies

VIEW

Solution

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 3 steps

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

A rotating methane molecule is described by the quantum numbers J, MJ, and K. (a) For methane, how many rotational states have an energy equal to hBJ(J + 1) with J= 8? (b) Now consider chloromethane. How many rotationalstates have an energy equal to hBJ(J + 1) with J = 8?
Calculate the rotational constant (B) for the molecule H12C14N, given that the H-C and C-N bond distances are 106.6 pm and 115.3 pm respectively.
The NOF molecule is an asymmetric rotor with rotational constants 3.1752 cm−1, 0.3951 cm−1, and 0.3505 cm−1. Calculate the rotational partition function of the molecule at (i) 25 °C, (ii) 100 °C.
Consider the rotational temperatures of the following hetero diatomic molecules: θr(CO) = 2.1 K, θr(HF) = 30.2 K. In which case would the classical approximation be accurate? Justify your answer.
The rotational constant for CO is 1.9314 cm−1 and 1.6116 cm−1 in the ground and first excited vibrational states, respectively. By how much does the internuclear distance change as a result of this transition?
Evaluate the rotational partition function of pyridine, C5H5N, at 25 °C given that ᷉ A = 0.2014 cm−1, ᷉ B = 0.1936 cm−1, ᷉ C = 0.0987 cm−1. Take the symmetry number into account.
Evaluate the rotational partition function at 298 K of (a) 1H35Cl. for which the rotational constant is 318 GHz, (b) 12C16O2, for which the rotational constant is 11.70 GHz.
Calculate the relative populations of the J = 2 and J = 1 rotational levels of HCI at 25 oC. For HCI the rotational constant is B =318.0 GHz.
Consider the rotational spectrum of a linear molecule at 298 K with a moment of inertia of 1.23×10−461.23\times10^{-46}1.23×10−46 kg m2 . (a) What is the frequency for the transition from J = 2 to J = 3? (b) What is the most populated rotational level for this molecule? Would the transition in (a) give the most intense signal in the rotational spectrum?
Estimate the rotational partition function of ethene at 25 °C given that ᷉ A = 4.828 cm−1, ᷉ B =1.0012 cm−1, and ᷉ C = 0.8282 cm−1. Take the symmetry number into account.
The H2O molecule is an asymmetric rotor with rotational constants 27.877 cm−1, 14.512 cm−1, and 9.285 cm−1. Calculate the rotational partition function of the molecule at (i) 25 °C, (ii) 100 °C.
Calculate the contribution of each normal mode to the molar vibrational heat capacity of H_2O (g) at 600 K.