The solubility of water in diethyl ether has been reported to be 1.468 % by mass.' Assuming that 23.0 mL of diethyl ether were allowed to become saturated with water before used, and that the 1.2 g magnesium was the limiting reagent, what percentage of the product is expected to be lost due to the water in the solvent if the ether is not anhydrous?
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- 0.1 g of the mixture of na2so4 and k2so4 is taken and 100 ml of solution is prepared. 10 ml of this prepared solution is placed in a beaker and some distilled water is added. A mass of 15.5 mg is obtained by precipitation with Bacl2 at PH=5, then filtering and bringing to a constant weight at 800 °C. Calculate the percentages of Na2so4 and K2so4 in the mixture accordingly.(1a) Pure benzophenane freezes at 66.6 °C. A solution of 7.75 g of biphenyl (C12H10; molar mass = 154.2g/mol) plus 200.08 g of benzophenane froze at 59.9 °C. Calculate the Kf of benzophenane in °C*kg/mol. (b) An unknown solution with possible cations (Ag+, Hg22+, Pb2+) is treated with 6M HCl and a white precipitate forms. Hot water is added to the precipitate, and a white solid remains after filtration. The white solid is treated with aqueous NH3, and the precipitate turns grey or black. The resulting solution is treated with HNO3 and no precipitate forms. What cations can you determine to be present, absent or maybe present? Explain your reasonThe distribution coefficient, KD (C water/C ether), between ether and water for aspirin at room temperature is 0.30. What weight of aspirin would be extracted by a single extraction with 300 mL of water from a solution of with a concentration of 0.67 M? Calculate the weight of aspirin which would be removed by three extractions with 100 mL portions of water. Compare the weight of solute extracted in single extraction process with the triple extraction process. Take note: The volume of the solution is 100ml
- Although other solvents are available, dichloromethane(CH₂Cl₂) is still often used to “decaffeinate” drinks because thesolubility of caffeine in CH₂Cl₂ is 8.35 times that in water.(a) A 100.0-mL sample of cola containing 10.0 mg of caffeine is extracted with 60.0 mL of CH₂Cl₂. What mass of caffeine re-mains in the aqueous phase? (b) A second identical cola sampleis extracted with two successive 30.0-mL portions of CH₂Cl₂.What mass of caffeine remains in the aqueous phase after each extraction? (c) Which approach extracts more caffeine?The distribution coefficient of an organic salt between hexane and water is 90. A quantity of 0.1 mol of the salt dissolved in 100ml of water. Predict how many moles of the salt will remain within the aqueous phase following extraction by using four 25ml of aliquots of hexane to extract the salt from the aqueous solutionAssume you dissolve 30.0 g of cobalt sulfate heptahydrate (CoSO4.7H2O) in 500 ml of a 1.0 MH2SO4 solution. Calculate the following for CoSO4.7H2O in this solution:(The Specific Gravity of 1.0 M H2SO4 @ 20°C is 1.0814 g/ml.) Molality, Mole fraction and Weight percentage
- Hexanoic acid was added to an immiscible biphasic solvent system, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D2) of hexanoic acid in water with respect to CCl4.Dissolved 0.273 grams of pure sodium oxalate (Na2C204) in distilled water and added sulfuric acid and titration the solution at 70 °C by using 42.68 ml of KMNO4 solution and has exceeded end point limits by using 1.46 ml of standard oxalic acid (H2 C204) with 0.1024 N. Calculate the normlity of KMNO4. Note that the molecular weight of sodium oxalate (Na2C204) = 134 and its equivalent weight = 67 * %3DOne litre of a saturated aqueous solution of Ag2SO4 (MW = 311.79 g mol- 1) at 25 °C is evaporated to dryness. 4.844 g of Ag2SO4 residue was produced. What is the solubility product (Ksp)?
- You are given a substance that is qually soluble in water and hexane (two immisible solvents) a) what is Kd B) if you start with 10g of the substance dissolved in 100ml of water and are given 100ml of hexane to extract with, algebriaically show that it is better to do two smaller extractions using 50 ml of hexane for each extraction than it is to do one extraction using 100ml of hexaneQ1. Dissolved 0.273 grams of pure sodium oxalate (Na,C,O.) in distilled water and added sulfuric acid and titration the solution at 70 ° C by using 42.68 ml of KMNO, solution and has exceeded end point limits by using 1.46 ml of standard oxalic acid (H; C;O.) with 0.1024 N. Calculate the normlity of KMN0.. Note that the molecular weight of sodium oxalate (Na,C,O.) = 134 and its equivalent weight = 67The following evidence was obtained from an experiment to determine the solubility of calcium chloride at room temperature. A sample of saturated calcium chloride solution was evaporated to dryness, and the mass of solid residue was measured.EvidenceVolume of solution (mL) = 15.0Mass of empty beaker (g) = 90.54Mass of beaker and residue (g) = 101.36The solubility of calcium chloride is g/100 mL