The Telluride ion was determined by indirect titration with EDTA. To a solution conta 50.00 mL of 0.08664M Zn(CIO4)2 plus 15 mL of 1 M acetate buffer (pH 4.5) were added mL of unknown telluride solution with vigorous stirring. The ZnTe precipitate was fi and washed with hot water. Then NH3 was added to the filtrate (which contained excess until the blue colour of Zn(NH3)42+ was observed. Titration of the filtrate with 0.07854 M I required 24.22 mL to reach the murexide end point. Calculate the molarity of telluride jon in the unknown

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.35QAP
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The Telluride ion was determined by indirect titration with EDTA. To a solution containing
50.00 mL of 0.08664M Zn(CIOA)2 plus 15 mL of 1 M acetate buffer (pH 4.5) were added 50.00
mL of unknown telluride solution with vigorous stirring. The ZnTe precipitate was filtered
and washed with hot water. Then NH3 was added to the filtrate (which contained excess Zn2+)
until the blue colour of Zn(NH3)42+ was observed. Titration of the filtrate with 0.07854 M EDTA
required 24.22 mL to reach the murexide end point.
Calculate the molarity of telluride ion in the unknown.
Transcribed Image Text:The Telluride ion was determined by indirect titration with EDTA. To a solution containing 50.00 mL of 0.08664M Zn(CIOA)2 plus 15 mL of 1 M acetate buffer (pH 4.5) were added 50.00 mL of unknown telluride solution with vigorous stirring. The ZnTe precipitate was filtered and washed with hot water. Then NH3 was added to the filtrate (which contained excess Zn2+) until the blue colour of Zn(NH3)42+ was observed. Titration of the filtrate with 0.07854 M EDTA required 24.22 mL to reach the murexide end point. Calculate the molarity of telluride ion in the unknown.
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