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The third paragraph should include a detailed explanation of the sources of error in Kinetics of Solvolysis of 2-chloro-2-methylpropane experiment. What experimental parameters will cause the rate constant to be larger or smaller? What are the limiting factors in the precision of the rate constant determination? What changes could you make to determine the rate constant for this reaction with better precision?

The third paragraph should include a detailed explanation of the sources of error in Kinetics of Solvolysis of 2-chloro-2-methylpropane experiment. What experimental parameters will cause the rate constant to be larger or smaller? What are the limiting factors in the precision of the rate constant determination? What changes could you make to determine the rate constant for this reaction with better precision?

Chemistry: The Molecular Science
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.3: Rate Law And Order Of Reactions
Problem 11.5PSP
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The third paragraph should include a detailed explanation of the sources of error in Kinetics of Solvolysis of 2-chloro-2-methylpropane experiment. What experimental parameters will cause the rate constant to be larger or smaller? What are the limiting factors in the precision of the rate constant determination? What changes could you make to determine the rate constant for this reaction with better precision? Here is my results www Kinetics dats template- Saved to my Mac Auloseve Home Insert Draw Page Lavout Formulas Data Review View V Tell me A Share -Comments 山,,。 “知。D. f S, K nt v Σ Callbri (Body) - 20 General Dekie v D四。 Cell Formatting as Tasle ty es Pata BIJ V Canditianal Farmat i Femar Sort a Find A Seralt vity Fiber Seleat P13 fx K Format Shape time (s) V(ml) V/Vinf 1-V/Vinf In(1-V/Vinf) k deviation from average k time (s) In(1-V/Vinf) o #DIV/O! 380 0.98 0.03738 0.962624 -0.038092441 -0.0001002 1.89576E-05 380 -0.0381 Fil 692 1.91 0.07285 0.927155 -0.07563469 -0.0001093 9.90214E-06 692 -0.0756 v Line 1102 3.03 0.11556 0.884439 -0.122801327 -0.0001114 7.76586E-06 1102 -0.1228 O Ne ine Sold line 1411 3.94 0.15027 0.849733 -0.162833063 -0.0001154 3.79823E-06 1411 -0.1628 1805 5.04 0.19222 0.80778 -0.213465138 -0.0001183 9.37591E-07 1805 -0.2135 O Gradient line 2263 6.31 0.24066 0.759344 -0.27530036 -0.0001217 2.45201E-06 2263 -0.2753 2810 7.66 0.29214 0.707857 -0.345513751 -0.000123 3.7578E-06 2810 -0.3455 3358 9.01 0.34363 0.656369 -0.421031868 -0.0001254 6.18091E-06 3358 -0.421 10 3976 10.31 0.39321 0.606789 -0.499574636 -0.0001256 6.44672E-06 3976 -0.4996 1 12 4432 11.34 0.43249 0.567506 -0.566504449 -0.0001278 8.62058E-06 4432 -0.5665 5051 12.04 0.45919 0.540809 -0.614689957 -0.0001217 2.49586E-06 5051 -0.6147 13 5678 13.73 0.52365 0.476354 -0.741594154 -0.0001306 1.14075E-05 5678 -0.7416 14 15 16 Average k average deviation from average 18 0.0001192 6.89356E-06 19
Transcribed Image Text:The third paragraph should include a detailed explanation of the sources of error in Kinetics of Solvolysis of 2-chloro-2-methylpropane experiment. What experimental parameters will cause the rate constant to be larger or smaller? What are the limiting factors in the precision of the rate constant determination? What changes could you make to determine the rate constant for this reaction with better precision? Here is my results www Kinetics dats template- Saved to my Mac Auloseve Home Insert Draw Page Lavout Formulas Data Review View V Tell me A Share -Comments 山,,。 “知。D. f S, K nt v Σ Callbri (Body) - 20 General Dekie v D四。 Cell Formatting as Tasle ty es Pata BIJ V Canditianal Farmat i Femar Sort a Find A Seralt vity Fiber Seleat P13 fx K Format Shape time (s) V(ml) V/Vinf 1-V/Vinf In(1-V/Vinf) k deviation from average k time (s) In(1-V/Vinf) o #DIV/O! 380 0.98 0.03738 0.962624 -0.038092441 -0.0001002 1.89576E-05 380 -0.0381 Fil 692 1.91 0.07285 0.927155 -0.07563469 -0.0001093 9.90214E-06 692 -0.0756 v Line 1102 3.03 0.11556 0.884439 -0.122801327 -0.0001114 7.76586E-06 1102 -0.1228 O Ne ine Sold line 1411 3.94 0.15027 0.849733 -0.162833063 -0.0001154 3.79823E-06 1411 -0.1628 1805 5.04 0.19222 0.80778 -0.213465138 -0.0001183 9.37591E-07 1805 -0.2135 O Gradient line 2263 6.31 0.24066 0.759344 -0.27530036 -0.0001217 2.45201E-06 2263 -0.2753 2810 7.66 0.29214 0.707857 -0.345513751 -0.000123 3.7578E-06 2810 -0.3455 3358 9.01 0.34363 0.656369 -0.421031868 -0.0001254 6.18091E-06 3358 -0.421 10 3976 10.31 0.39321 0.606789 -0.499574636 -0.0001256 6.44672E-06 3976 -0.4996 1 12 4432 11.34 0.43249 0.567506 -0.566504449 -0.0001278 8.62058E-06 4432 -0.5665 5051 12.04 0.45919 0.540809 -0.614689957 -0.0001217 2.49586E-06 5051 -0.6147 13 5678 13.73 0.52365 0.476354 -0.741594154 -0.0001306 1.14075E-05 5678 -0.7416 14 15 16 Average k average deviation from average 18 0.0001192 6.89356E-06 19
AutoSave a Kinetics data template OFF Home Insert Page Layout Formulas Data Review View Tell me 2 Share O Comments Calibri (Body) v 14 A A ab v A Insert v General E Delete v = = = $ • % 9 | 8 8 Cell Formatting as Table Styles Paste s v A v Sensitivity .00 Conditional Format Sort & Filter Find & Select Ideas BIUV H Format v fx Format Shape In(1/v/vinf) vs. Time 0.1 > Fill v Line i .. ....... ........ 1000 2000 3000 4000 5000 6000 No line Solid line -0.1 Gradient line -0.2 -0.3 -0.4 -0.5 -0.6 y = -0.0001x + 0.014 R? = 0.9979 -0.7 -0.8 Chart1 data and calculations 114% In(1-V/Vinf)
Transcribed Image Text:AutoSave a Kinetics data template OFF Home Insert Page Layout Formulas Data Review View Tell me 2 Share O Comments Calibri (Body) v 14 A A ab v A Insert v General E Delete v = = = $ • % 9 | 8 8 Cell Formatting as Table Styles Paste s v A v Sensitivity .00 Conditional Format Sort & Filter Find & Select Ideas BIUV H Format v fx Format Shape In(1/v/vinf) vs. Time 0.1 > Fill v Line i .. ....... ........ 1000 2000 3000 4000 5000 6000 No line Solid line -0.1 Gradient line -0.2 -0.3 -0.4 -0.5 -0.6 y = -0.0001x + 0.014 R? = 0.9979 -0.7 -0.8 Chart1 data and calculations 114% In(1-V/Vinf)
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