5.9 4.0 H H for R-H R: + H-CI: + H H 2.7 1.0

Q: For the following molecule, identify the position which is the most likely to undergo EAS reaction:…

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Q: The analogous reaction of trans-1,2-dichloroethylene with benzyne produces the same cIS and trans-…

A: As per the guideline, since you have asked multiple questions, we have solved the first question for…

Q: R. Atkinson (J. Phys. Chem. Ref. Data 26, 215 (1997)) has reviewed a large set of rate constants…

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Q: R. Atkinson (J. Phys. Chem. Ref. Data 26, 215 (1997)) has reviewed a large set of rate constants…

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Q: In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different…

A: Here bridging system matters.  Any intermediate is not stable at bridging position.  Hence reaction…

Q: In the free radical chlorination of isobutane, what is the % yield of product X and Y, respectively?…

A:

Q: In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different…

A: 1. tertiary C-H bonds are more reactive. 2. major monochloro substitution product is a because a…

Q: (a) State the differences between homolytic and heterolytic cleavages. (b) Consider the following…

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Q: Draw three isomers for a chloro alkane having 4 carbons and identify them as primary, secondary and…

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Q: diphenylcyclopentadienone dimer ("Dimer") from two "Monomers" has been determined to have a rate…

A: We will use second order reaction  formula becais unit is M-1min-1

Q: Identify the TRUE statement about the transition state(s) of an SN2 mechanism. Select one: a. The…

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Q: The rate law for the hydrogenation (H) of ethylene (E) to form ethane (A) over a cobalt-molybdenum…

A: The rate law for the hydrogenation reaction of ethylene to form ethane over a molybdenum catalyst is…

Q: Calculated Heats of Reaction, AH=AHf(R')+ AHf(CH) – AHF(RCD, in kJ/mol: R=n-butyl R= sec-butyl R=…

A: Difference in Heat of reaction of alkyl halide can be explained on the basis of stability of…

Q: In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different…

A: Reactivity order: Primary < Secondary < Tertiary

Q: Looking at the Jablonski diagram below, 13 processes are indicated (1-13), which is the proper order…

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Q: A substitution reaction is carried out on 2-iodobutane with sodium halide in alcohol solvent at…

A: In 1st question

Q: The compound below is treated with chlorine in the presence of light. CH3 CH3CHCH,CH3 Draw the…

A: The answer is given as follows

Q: The rate law for the reaction of HO- with tert-butyl bromide to form an elimination product in 75%…

A: Data given: K2 = 7.1×10-5 K1 = 1.5×10-5 Concentration of hydroxide ion = 5.0 M

Q: Consider the photohalogenation of 2,3-dimethylbutane using Cl2(g). Draw the possible monohalogenated…

A: The structure of 2,3-dimethylbutane is  The reactivity of 3° hydrogens are 5.2 times more than 1°…

Q: In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different…

A: Chlorination of alkane having primary, secondary and quarternary carbon.

Q: 5 a) For each of the reactions below, describe a suitable reaction mechanism, stating the reaction…

A: Since you have posted a question with multiple sub-parts, we will solve the first three subparts for…

Q: In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different…

A:

Q: The radical halogenation of 2-methylpropane gives two products: (CH3)2CHCH2X (primary) and (CH3)3CX…

A: % of tertiary = 100 x amount of tertiary/Total amount of all three

Q: 13. Provide a mechanism for the chain radical mechanism, using curved arrow formalism, of the…

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Q: In the presence of a small amount of bromine, the following light-promoted reaction has been…

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Q: The second-order rate constant (in units of M-1s-1) for acid-catalyzed hydration at 25 °C is given…

A: a) the relative rate of hydration of given alkenes is shown in below pic

Q: Which of the following is not a possible termination step in the free radical chlorination of…

A: In any free radical reaction, the three steps involved are, 1) Initiation step: This is the step of…

Q: (a) State the differences between homolytic and heterolytic cleavages. (b) Consider the following…

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Q: 10. The following Diels-Alder cycloaddition was recently performed by Mukherjee et al. CH,Cl, CO,Et…

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Q: The rate law for the reaction of HO- with tert-butyl bromide to form an elimination product in 75%…

A: The percentage of reaction that takes place by E2 mechanism can be expressed as follows-

Q: Provide a radical mechanism and the radical product for the ring- opening reaction of the following…

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Q: 8. Propose a mechanism for the light-Initiated free-radical monofluorination of ethane: CH,CH, + F2…

A: This is a example of flouration by free radical substitution reaction.

Q: 7.) Carbocations are high energy intermediates in organic synthesis that are open-shelled carbon…

A: The given reaction (b) gave two regioisomeric products. This is because the given carbocation (b) is…

Q: following compounds are major products of an elimination reaction with an alkyl halide. Determine…

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Q: 27. An alternative step in the free radical chlorination mechanism, of methane might be as follows:…

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Q: 6) The substitution reaction below to produce 1-iodobutane was performed using 1-bromobutane at a…

A: Primary alkyl bromide gives primary alkyl iodide by reacting with sodium iodide in acetone solvent.…

Q: 17. Draw the molecular orbital diagrams for a photochemical (hv) reaction between two molecules of…

A: Here we have to predict the product for the 2nd question and the mechanism and for the first…

Q: Which of the following represents the transition state of the rate-determining step in the SN1…

A: We need to determine the rate-determining step in the SN1 reaction between tert-butyl chloride and…

Q: In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different…

A: Chlorination takes place in the presence of UV light/radical initiators is called radical…

Q: Draw all constitutional isomers formed by monochlorination of 2-methylbutane. It is a…

A: Chlorination reaction is replacing the hydrogen atom of alkyl or aromatic compound with chlorine…

Q: 1. An SN2 reaction exhibits second-order kinetics. What happens to the rate of an SN2 reaction under…

A: Given: Nucleophilic substitution bimolecular Reaction which follows second order kinetics To find:…

Q: The rate law for an addition reaction of bromine to an alkene is rate = k[alkene][Br,]? The order of…

A: We have to predict order and the unit of rate constant.

Q: Bond Bond energy (kcal/mol) B. Given in the table are the bond energies (in kcal/mol) of some of the…

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Q: The reaction of 2-bromopropane and sodium ethoxide in ethanol reacts 6.7 times 1). faster than…

A: We have to explain the mechanism for the following given reaction as follows in step 2:

Q: Which of the following is not a possible termination step in the free radical chlorination of…

A: In any free radical reaction, the three steps involved are, 1) Initiation step : This is that step…

Q: The rate law for an addition reaction of bromine to an alkene is rate = k [alkene] [Br,] The order…

A:

Q: C(CH3)3 e.

A: