Answered: The total pressure of the following…

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 25E: At 40C, H2O2 (aq) will decompose according to the following reaction: 2H2O2(aq)2H2O(l)+O2(g) The...

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Question

The total pressure of the following system is used to monitor the progress of the chemical reaction.
SO2Cl2(g) → SO2(g) + Cl2(g)
The reaction is initiated, and the following data are obtained:
Time (h)
0
3
6
9
12
15
PTotal (kPa)
11.07
14.79
17.26
18.90
19.99
20.71
??????2????2
??????2
??????2
Additional information:
As the reaction proceeds, stoichiometry dictates that for every mole of SO2Cl2 that dissociates one
mole of each of SO2 and Cl2 is produced. Defining the extent of dissociation/reaction as ξ, and the
initial pressure as P0, the total pressure is given by:
???????????? = ??????2????2 + ??????2 + ??????2 = (??0 − ξ) + ξ + ξ

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