The total z component of the spin angular momentum operator for an N-electron system is N Ŝz total j=1 a) Show that 1 Visa(1) yısB(1)| v2|Y1sa(2) Vısß(2) || is an eigenfunction of Sz4otal· What is the eigenvalue? b) Show that Vısa(1) WisB(1) W2,¤(1) 1 V1sa(2) WisB(2) V2,¤(2) V3! Vısa(3) WısB(3) W2,¤(3) is an eigenfunction of Ŝz4otal. What is the eigenvalue?

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter10: Introduction To Quantum Mechanics
Section: Chapter Questions
Problem 10.40E
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Please show work for parts a and b with explanation thank you
The total z component of the spin angular momentum operator for an N-electron system is
N
Ŝ,stotal=
j=1
a) Show that
1Visa(1) yısB(1)|
v2|V1sa(2) yısß(2)
is an eigenfunction of Ŝ„total· What is the eigenvalue?
b) Show that
Visa(1) VisB(1) W2,a(1)
1
Vısa(2) Wısß(2) ¥2,¤(2)
V3!
V1,a(3) Yısß(3) V2,¤(3)
Y =
is an eigenfunction of Ŝ,total. What is the eigenvalue?
Transcribed Image Text:The total z component of the spin angular momentum operator for an N-electron system is N Ŝ,stotal= j=1 a) Show that 1Visa(1) yısB(1)| v2|V1sa(2) yısß(2) is an eigenfunction of Ŝ„total· What is the eigenvalue? b) Show that Visa(1) VisB(1) W2,a(1) 1 Vısa(2) Wısß(2) ¥2,¤(2) V3! V1,a(3) Yısß(3) V2,¤(3) Y = is an eigenfunction of Ŝ,total. What is the eigenvalue?
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ISBN:
9781133958437
Author:
Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,