The vapor pressures of solid ammonia and liquid ammonia as a function of temperature respectively are given by In p = 23.03 - 3754/T and by In p = 19.09 -3063/T (where T is in Kelvin and p is in mm Hg). a. Calculate the triple temperature and pressure (Tt, pt) in the appropriate units. b. Calculate the latent heat of sublimation and the latent heat of evaporation at the triple point. c. Sketch the p-T diagram of the gas above the triple point.

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Chapter14: Liquids And Solids
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The vapor pressures of solid ammonia and liquid ammonia as a
function of temperature respectively are given by In p = 23.03 -
3754/T and by In p = 19.09 −3063/T (where T is in Kelvin and p is
in mm Hg).
a. Calculate the triple temperature and pressure (Tt, pt) in the
appropriate units.
b. Calculate the latent heat of sublimation and the latent heat of
evaporation at the triple point.
c. Sketch the p-T diagram of the gas above the triple point.
Transcribed Image Text:The vapor pressures of solid ammonia and liquid ammonia as a function of temperature respectively are given by In p = 23.03 - 3754/T and by In p = 19.09 −3063/T (where T is in Kelvin and p is in mm Hg). a. Calculate the triple temperature and pressure (Tt, pt) in the appropriate units. b. Calculate the latent heat of sublimation and the latent heat of evaporation at the triple point. c. Sketch the p-T diagram of the gas above the triple point.
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