TiCl(Cp)2(CN)] and [TiCl(Cp)2(NH3)]Cl  [IrMe(PMe3)4] and [Ir(C≡C-Ph)(PMe3)4]   - Include the calculation for the complexes - Total electrons - Different Ligands, Oxidation State Choose the more stable complex and discuss the reason based on the 3 main point above.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 117QRT
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Choose the more stable complex from each pair of the complexes? Give the reason for each choice. 

 

  1. [TiCl(Cp)2(CN)] and [TiCl(Cp)2(NH3)]Cl 
  2. [IrMe(PMe3)4] and [Ir(C≡C-Ph)(PMe3)4]

 

- Include the calculation for the complexes

- Total electrons

- Different Ligands, Oxidation State

Choose the more stable complex and discuss the reason based on the 3 main point above. 

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