pls solve this asap 20.77. The nitration of methanol, CH;OH, by nitrous acid isthought to proceed via the following mechanism:CH;OH + H+CH;OH,*CH;OH, *→ CH;* + H,0CH;* + NO,→ CH;NO2Suppose the first step is the RDS. What is the expected ratelaw in terms of the original reactants?

Answered: Image /qna-images/answer/d0da908e-917d-4548-9f6c-0015084c15f1.jpg

20.77. The nitration of methanol, CH;OH, by nitrous acid is thought to proceed via the following mechanism: → CH;OH,* → CH;* + H,O CH;OH + H* - CH;OH,* CH,* + NO, → CH;NO, Suppose the first step is the RDS. What is the expected rate law in terms of the original reactants?

20.77. The nitration of methanol, CH;OH, by nitrous acid is thought to proceed via the following mechanism: → CH;OH,* → CH;* + H,O CH;OH + H* - CH;OH,* CH,* + NO, → CH;NO, Suppose the first step is the RDS. What is the expected rate law in terms of the original reactants?

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter10: Organohalides

Section10.SE: Something Extra

Problem 19MP: The formation of Br2 from NBS first involves the reaction of NBS with HBr to form an iminol...

See similar textbooks

Related questions

Q: ) What is the mole fraction of HCl in a solution that is prepared by dissolving 25.5 g of HCl in…

Q: Which of the following statements about an SN1 reaction is true? A. the reaction occurs in one-step…

A: Transition state can be defined as the state that corresponds to the highest energy in reaction…

Q: En un envase de reacción se añade la misma cantidad de los dos reactivos. Ocurre la siguiente…

A: The equilibrium reaction given is, => Given: Same concentration of both reactants A and D are…

Q: Consider this initial rate data at a certain temperature in the table for the reaction [OCI-],…

Q: CH3 CH;NH2 .C. H, CH3CH CI CH3OH CH,CH=CHCH,Br

A: ->In nucleophilic substitution reaction(SN2) the configuration of chiral center get reversed .…

Q: Consider an electrochemical cell based on the following cell diagram: PtI Pu3"(ac), Pu1"(ac)||…

Q: R E H R Cu rea-brom Pit

Q: A known organic acid has pKa = 3.80. What is the percent dissociation of this organic acid in a…

Q: Choose the statements that are correct. (Select all that apply.) OIn the isothermal expansion of an…

A: Now ∆U= q- w So in isothermal expansion ∆U = 0 so q=w So ist option is incorrect Yes when entropy…

Q: Trial 1: Initial pH= 3.92mL Mass of KHP and Paper= 0.868g Mass of paper= 0.357g Mass of KHP= 0.511g…

A: The titration curves given for both the trials are,

Q: Identify the two reactions below that will give the indicated azo dye in good yield. Make sure to…

Q: + 5.8234 %3D 7a) 7) For the equation: log, (VPPa) = (-1234 K). calculate the: a ) ΔΗ vap 7b) b) Tnvp…

A: The equation given is, => log(VPKPa) = -1234T + 5.8234

Q: The equilibrium constant, K, for the folowing reaction is 1.20x1o2 at 500 K PCI,(9) PCIy(0)+ Clzla)…

A: Equilibrium constant K = 1.20 * 10-2

Q: 11. Classify substances listed as Lewis acids or bases: a/PH3 b/BH3 c/SiCl4 d/SnCl2 e/AsCls

Q: 2) Draw the intermediate and the product. slow H* =+ H,0 fast

A: The intermediate and the product is :

Q: Cu(NH,), complex K, = 2.09 × 103 For the aqueous at 25 °C. Suppose equal volumes of 0.0020M Cu(NO,),…

A: Here the complex formation constant of [Cu(NH3)4]2+ is 2.09×10^13 , hence initially the reaction…

Q: For the aqueous Cd(CN), complex K, = 6.03 x 10° at 25 °C. Suppose equal volumes of 0.0040M Cd(NO,)…

A: Given: Concentration of Cd(NO3)2 = 0.0040 M Concentration of NaCN = 0.80 M And equal volume of both…

Q: apply.

A: According to the question, we need to determine which elements can be isolated by electrolysis of…

Q: A voltaic cell is constructed with two Zn2+-Zn electrodes, where the half-reaction is: Zn2+ + 2e -…

Q: The equilibrium constant, K, for the following reaction is 1.20x102 at 500 K. PCI,(9) PCI,(9) +…

Q: Ag2S→2Ag + S; A) Determine the moles of Ag2S needed when 25 moles of Ag are produced. B) Determine…

Q: What is the correct IUPAC name for the following compound? CH3- CH- CHz-CH-CH-CH3 CH3 OH

A: Rule of IUPAC- 1) Longest chain as parent chain. 2) Numbering start from those side where more prior…

Q: 425 Time Series in the North Pacific 8.30 Mauna Loa Atmospheric CO2 (ppm) ALOHA seawater PCO2 insitu…

A: A question based on tools in analytical chemistry that is to be accomplished.

Q: Given the following list of lonization Energies for an unknown element, how many valence electrons…

A: Ionization energy is the energy required to remove electron from valance shell of an atom . If the…

Q: For the reaction NI2*(aq) + 2FE2*(aq) – NI(s) + 2FE3*(aq), the standard cell potential Ecell is…

Q: The standard cell potential (E°cell) for the voltaic cell based on the reaction below is __________…

A: According to question, the answer must be 1.10 V but none of the option is 1.10 V. The solution…

Q: Arrange the following ions in order of increasing ionic radii: ( Ca2+, K+, Al3+)(. Your answer…

A: Cation are smaller than their parent atoms ionic radius decrease along left to right in period…

Q: What is the daughter nucleus produced when Cu59 undergoes positron emission?

A: when positron emitted proton changes to neutron

Q: What is the empirical formula for a compound containing 64.95% Tin 17.54% sulfur and the remainder…

A: Molecular formula: In a molecular formula we describe the number of atoms of all the elements…

Q: Consider an electrochemical cell based on the following cell diagram ven that the standerd cell emf…

Q: Eventhough there may be some advantages using nuclear power has many disadvantages and should not be…

A: Nuclear Technology have many advantages over other Technologies and Disadvantage too.

Q: 28 The following reaction is endothermic: 30,g)=20,g) If the reaction is at equilibrium, tell…

A: Le Chatelier's principle: This principle is used to predict the effect of a change in conditions on…

Q: Containing a Single unkown Solution is added to 3. test tubes Calion following added and The anions…

A: To predict the cation , we would use solubility rules to check which cation form insoluble Compound…

Q: Following the net ionic equation of the reaction: Na + Feso4 - NazsO4 + Fe How should its Keq be…

A: ->Na(s) + FeSO4(aq) ----> Na2SO4(aq) + Fe(s) ->when one specie get oxidized and other get…

Q: A sample of KHP. KHCaH.Os, weighing 2.035 g is titrated with NaOH and backtitrated with HCI. NaOH…

A: Given: Mass of sample of KHP =2.035 g Volume of NaOH required =23.20 mL Volume of HCl required…

Q: Write a brief introduction about oxidation–reduction and double displacement.

Q: plicable monosaccharides. Sugar Fischer Haworth Chair a CHO HO OH но H- H OH ČH2OH D-idose…

Q: A mixture of gases at 1 atm (760 mmHg) contains CO2, N2, and O2. The partial pressure of CO2 is 0.3…

A: For given mixture of gases , total pressure is given as sum of partial pressure of all gases.

Q: Determine the standard enthalpy of reaction, AH°n, of the reaction below, given the following…

A: Mg(s) + 2H2O(l) ---> Mg(OH)2(s) + H2(g)

Q: A galvanic cell has the overall reaction: 2Fe(NO3)2(aq) + PBINO3)2(aq) → 2Fe(N03)3(aq) + Pb(s) Which…

A: At cathode , reduction takes place . So we would first write oxidation states to check which species…

Q: Order following liquids from most soluble to least soluble in water. Simply explain your answer.…

Q: a) 47 g of KCl dissolved in enough water to give 375 mL of solution b) 82.6 g of sucrose, C,,H„0,1,…

A: As we know the molarity formula Molarity = (weight of solute/molarmass of solute)×(1000/volume of…

Q: Draw the structure(s) of the major organic product(s) of the following reaction. 1. KMno, I NAOH 2.…

A: The alkyl group attached to the benzene ring having at least one hydrogen atom at the key atom can…

Q: If an orbital has a principle quantum mber of three (3), what are the possible lues of the orbital…

A: The azimuthal (angular) quantum number varies between 0 and (n-1) here n represent principal…

Q: b. Complete the following chart using the information given. Correctly write the name or formula of…

A: "To get remaining sub-parts solved please repost the complete question and mention the sub-parts to…

Q: The cell potential for this reaction is V when the concentration of [Cu2*] = 1.0 x 105 M and [Zn2*]=…

Q: Consider a Galvanic cell constructed from the following half cells, linked by an external circuit…

Q: जोण्ट को खेतेपलेणच्छ ली a) (z) 2,3-dime thyl-3-hexene 1,3-hexa digme (b)

A: Given : IUPAC name of compounds (Z) 2,3-dimethyl-3-hexene 1,3-hexadiyne To draw :- structure of…

Q: Which of the following statements about the binding of oxygen to deoxyhemoglobin is correct?…

A: Which of the following statements is correct about binding of oxygen to deoxyhemoglobin ?

Q: solubity use olubity rules predict Whether Or not a double - replacmant reaction w. I! OCcur between…

A: The compounds given are AgNO3, KClO4 and NH4Br.

Question

pls solve this asap

20.77. The nitration of methanol, CH;OH, by nitrous acid is
thought to proceed via the following mechanism:
CH;OH + H+
CH;OH,*
CH;OH, *
→ CH;* + H,0
CH;* + NO,
→ CH;NO2
Suppose the first step is the RDS. What is the expected rate
law in terms of the original reactants?

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

The reaction between peroxodisulphate (VI) ions, S2O82- and iodide ions, I- can be catalyzed by iron(III) ions, Fe3+. Suggest a mechanism for the catalytic reaction.
[Rh(PPh3)3Cl] is a precatalyst that can be activated by dissociation of a phosphine ligand to form an active catalyst, B, which is used in the hydrogenation of alkenes. The active catalyst can then undergo oxidative addition in the presence of H2 to form complex C. Propene coordinates to C to form complex D, which then undergoes a 1,2- insertion step to form E. Reductive elimination of propane from E regenerates the active catalyst B. Draw complexes B – E and hence provide a full catalytic cycle, including the activation step, for the hydrogenation of propene
3. Obtain acetophenone and acetaldehyde by reaction of glycols with periodic acid. Justify your answer with the reaction mechanism.
The rate constant for the uncatalyzed reaction of two molecules of glycine ethyl ester to form glycylglycine ethyl ester is 0.6 M- 1s - 1. In the presence of Co2 +, the rate constant is 1.5 * 106 M- 1s - 1. What rate enhancement does the catalyst provide?
which is the best method for the preparation of H2O2 in laboratory?
The formation of Br2 from NBS first involves the reaction of NBS with HBr to form an iminol intermediate and molecular bromine. The intermediate then undergoes acid-catalyzed tautomerism to form succinimide, the byproduct of the reaction. Propose a curved-arrow mechanism for the conversion of NBS into succinimide that also accounts for the formation of Br2.
Propose the structures for hydrocarbons (and give the organic reaction) that give the following products on oxidative cleavage with KMnO 4 or O 3 .
Propose the structures for hydrocarbons (and give the organic reaction) that give the following products on oxidative cleavage with KMnO 4 or O 3 . EXPLAIN
4b）Give the mechanisms for the following:
The mechanism of the Fischer esterification was controversial until 1938, when IrvingRoberts and Harold Urey of Columbia University used isotopic labeling to follow thealcohol oxygen atom through the reaction. A catalytic amount of sulfuric acid was addedto a mixture of 1 mole of acetic acid and 1 mole of special methanol containing the heavy18O isotope of oxygen. After a short period, the acid was neutralized to stop the reaction,and the components of the mixture were separated.H2SO4OCH3 C O H CH3 O H CH3 C O CH3 H2OO18 + +(a) Propose a mechanism for this reaction.(b) Follow the labeled 18O atom through your mechanism, and show where it is found inthe products.(c) The 18O isotope is not radioactive. Suggest how you could experimentally determinethe amounts of 18O in the separated components of the mixture
drug synthesis from corey-kim oxidation
For the base-catalysed hydrolysis of 3-bromo-3-methylhexane (i.e. reaction with the nucleophile OH-): For the reaction intermediate, draw its structure and give the VSEPR description of the geometry at the reaction centre Give the names and draw the structures of the two reaction products. Explain your conclusions.