Use the bond energies from the table in the reference sheet to determine the approximate enthalpy change of the following reaction. H2(g) + Br2(g)  --> 2HBr(g)

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
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Chapter34: Particle Size Determination
Section: Chapter Questions
Problem 34.11QAP
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Use the bond energies from the table in the reference sheet to determine the approximate enthalpy change of the following reaction.

H2(g) + Br2(g)  --> 2HBr(g)

AT&T
11:57 AM
Exam 3 Reference.pdf
Na
Mg
12
AI
Si
CI
09
15
18
21
2.5
3.0
K
Ca
Sc
TI
V
Cr
Mn
Fe
Co
Ni
Cu
19
Zn
16
Ga
Ge
Se
Br
08
10
13
15
16
16
15
19
19
16
18
20
24
28
Rb
To
Pd
22
Ag
19
Te
Sr
Y
Zr
Nb
Мо
Cd
In
Sn
Sb
OB
10
12
14
1.6
1.8
19
17
17
18
21
25
Ba La-Lu Hf
1.0-12
Cs
Та
1.5
Re
Os
Ir
Pt
Au
24
TI
Pb
Bi
Hg
19
Po
20
At
22
0.7
0.9
13
1.7
19
22
22
22
18
19
19
Np-No
14-13
Fr
Ra
Ac
Th
Pa
0.7
09
11
13
14
1.4
Electronegativity
difference between
bonding atoms
Bond type
Zero
Pure covalent
Covalent
Bond Type Electronegativity Difference
character
decreases;
ionic character
increases.
Intermediate
Polar covalent
pure covalent
< 0.4
polar covalent
between 0.4 and 1.8
Large
lonic
ionic
> 1.8
Formal Charge = # valence e - nonbonding e - ½ bonding e
ΔΗΣΣ(ΔΗ(bonds broken)) + Σ (ΔΗ(bonds formed)
Bond
Bond Energy (kJ/mol)
С-Н
415
O-H
464
Н-Н
436
С-О
350
C=0
1080
Br-Br
190
Н-Br
370
Li,
Bez
B2
C2
N2
O2
F2
Nez
opx
O2px
T2py: 2pz
O2px
O25
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Transcribed Image Text:AT&T 11:57 AM Exam 3 Reference.pdf Na Mg 12 AI Si CI 09 15 18 21 2.5 3.0 K Ca Sc TI V Cr Mn Fe Co Ni Cu 19 Zn 16 Ga Ge Se Br 08 10 13 15 16 16 15 19 19 16 18 20 24 28 Rb To Pd 22 Ag 19 Te Sr Y Zr Nb Мо Cd In Sn Sb OB 10 12 14 1.6 1.8 19 17 17 18 21 25 Ba La-Lu Hf 1.0-12 Cs Та 1.5 Re Os Ir Pt Au 24 TI Pb Bi Hg 19 Po 20 At 22 0.7 0.9 13 1.7 19 22 22 22 18 19 19 Np-No 14-13 Fr Ra Ac Th Pa 0.7 09 11 13 14 1.4 Electronegativity difference between bonding atoms Bond type Zero Pure covalent Covalent Bond Type Electronegativity Difference character decreases; ionic character increases. Intermediate Polar covalent pure covalent < 0.4 polar covalent between 0.4 and 1.8 Large lonic ionic > 1.8 Formal Charge = # valence e - nonbonding e - ½ bonding e ΔΗΣΣ(ΔΗ(bonds broken)) + Σ (ΔΗ(bonds formed) Bond Bond Energy (kJ/mol) С-Н 415 O-H 464 Н-Н 436 С-О 350 C=0 1080 Br-Br 190 Н-Br 370 Li, Bez B2 C2 N2 O2 F2 Nez opx O2px T2py: 2pz O2px O25 ( Previous 2 Dashboard Calendar Тo Do Notifications Inbox +Decreasing electroneg
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