Use the equipartition principle to estimate the values of γ = Cp/CV for gaseous ammonia and methane. Do this calculation with and without the vibrational contribution to the energy. Which is closer to the experimental value at 25 °C?

Use the equipartition principle to estimate the values of γ = Cp/CV for gaseous ammonia and methane. Do this calculation with and without the vibrational contribution to the energy. Which is closer to the experimental value at 25 °C?

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter2: The First Law Of Thermodynamics

Section: Chapter Questions

Problem 2.92E

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Question

Use the equipartition principle to estimate the values of γ = C_p/C_V for gaseous ammonia and methane. Do this calculation with and without the vibrational contribution to the energy. Which is closer to the experimental value at 25 °C?

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