Use the molar bond enthalpy data in the table to estimate Bond kJ - mol-1 Bond kJ - mol- the value of AHin for the equation. О-Н 464 C=N 890 0–0 142 N-H 390 NH, (g) + 20,(g) → HNO, (g) + H,O(g) С-О 351 N-O 201 The bonding in the molecules is shown. O=0 502 N=N 418 C=0 730 N=O 607 + С-С 347 F-F 155 C=C 615 Cl-CI 243 C=C 811 Br-Br 192 С-Н 414 Н-Н 435 С-F 439 Н-F 565 C-CI 331 H-CI 431 С-Br 276 Н-Br 368 С-N 293 H-S 364 C=N 615 S-S 225 Activate WinkJomol-

Use the molar bond enthalpy data in the table to estimate Bond kJ - mol-1 Bond kJ - mol- the value of AHin for the equation. О-Н 464 C=N 890 0–0 142 N-H 390 NH, (g) + 20,(g) → HNO, (g) + H,O(g) С-О 351 N-O 201 The bonding in the molecules is shown. O=0 502 N=N 418 C=0 730 N=O 607 + С-С 347 F-F 155 C=C 615 Cl-CI 243 C=C 811 Br-Br 192 С-Н 414 Н-Н 435 С-F 439 Н-F 565 C-CI 331 H-CI 431 С-Br 276 Н-Br 368 С-N 293 H-S 364 C=N 615 S-S 225 Activate WinkJomol-

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter12: Thermodynamic Processes And Thermochemistry

Section: Chapter Questions

Problem 52P

See similar textbooks

Similar questions

The enthalpy of combustion of diamond is -395.4 kJ/mol. C s, dia O2 g CO2 g Determine the fH of C s, dia.
Would the amount of heat absorbed by the dissolution in Example 5.6 appear greater, lesser, or remain the same if the heat capacity of the calorimeter were taken into account? Explain your answer.
sample of natural gas is analyzed and found to be88.4% methane (CH4) and 11.6% ethane (C2H6) bymass. The standard enthalpy of combustion of methaneto gaseous carbon dioxide (CO2) and liquid water (H2O) is -891 kJ/mol. Write the equation for the combustionof gaseous ethane to carbon dioxide and water.Calculate the standard enthalpy of combustion of ethaneusing standard enthalpies of formation from Table R-11on page 975. Using that result and the standard enthalpyof combustion of methane in Table 15.3, calculate theenergy released by the combustion of 1 kg of natural gas.
The heat of neutralization, Hneut, can be defined as the amount of heat released (or absorbed), q, per mole of acid (or base) neutralized. Hneut for nitric acid is -52 kJ/mol HNO3. At 27.3C, 50.00 mL of 0.743M HNO3 is neutralized by 1.00 M Sr(OH)2 in a coffee-cup calorimeter. (a) How many mL of Sr(OH)2 were used in the neutralization? (b) What is the final temperature of the resulting solution? (Use the assumptions in Question 11.)
Find the enthalpies of the combustion reactions for methane through n-octane. Plot them versus the number of carbon atoms in the molecule, and determine an equation that gives H for the combustion of a given hydrocarbon. Then use the equation to predict the enthalpy of combustion for n-C12H26 and compare it to experimental values.
9.99 The chemical reaction BBr3(g)+BCl3(g)BBr2Cl(g)+BCl2Br(g) , has an enthalpy change very close to zero. Using Lewis structures of the molecules, all of which have a central boron atom, provide a molecular-level description of why H for this reaction might be very small.
The enthalpy change for the following reaction is 393.5 kJ. C(s,graphite)+O2(g)CO2(g) (a) Is energy released from or absorbed by the system in this reaction? (b) What quantities of reactants and products are assumed? (c) Predict the enthalpy change observed when 3.00 g carbon burns in an excess of oxygen.
Although the gas used in an oxyacetylene torch (Figure 5.7) is essentially pure acetylene, the heat produced by combustion of one mole of acetylene in such a torch is likely not equal to the enthalpy of combustion of acetylene listed in Table 5.2. Considering the conditions for which the tabulated data are reported, suggest an explanation.
When one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of neutralization.) At 23.7C, 25.0 mL of 0.475 M H2SO4 is neutralized by 0.613 M KOH in a coffee-cup calorimeter. Assume that the specific heat of all solutions is 4.18J/gC, that the density of all solutions is 1.00 g/mL, and that volumes are additive. (a) How many mL of KOH is required to neutralize H2SO4? (b) What is the final temperature of the solution?
The thermochemical equation for the burning of methane, the main component of natural gas, is CH4(g)+2O2(g)CO2(g)+2H2O(l)H=890kJ (a) Is this reaction endothermic or exothermic? (b) What quantities of reactants and products are assumed if H = 890 kJ? (c) What is the enthalpy change when 1.00 g methane burns in an excess of oxygen?
Write reactions for which the enthalpy change will be a. Hf for solid aluminum oxide. b. the standard enthalpy of combustion of liquid ethanol, C2H5OH(l). c. the standard enthalpy of neutralization of sodium hydroxide solution by hydrochloric acid. d. Hf for gaseous vinyl chloride, C2H3Cl(g). e. the enthalpy of combustion of liquid benzene, C6H6(l). f. the enthalpy of solution of solid ammonium bromide.
Calculate the standard enthalpy of combustion for benzene, C6H6. C6H6() + 15/2 O2(g) 6 CO2(g) + 3 H2O() rH = ? The enthalpy of formation of benzene is known [rH[C6H6()] = +49.0 kJ/mol], and other values needed can be found in Appendix L.