Use the valence electron molecular orbital diagram for O2 to propose ground state O2 ions that satisfy the following conditions: (i) An O2 ion that is paramagnetic and that has a non-integer bond order. (li) An O2 ion that is paramagnetic and that has an integer bond order. (ili) An O2 ion that is diamagnetic and that has a bond order of 3

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter6: Quantum Mechanics And Molecular Structure
Section: Chapter Questions
Problem 21P
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a) Use the valence electron molecular orbital diagram for O2 to propose ground state O2 ions that satisfy the following conditions:
(i) An O2 ion that is paramagnetic and that has a non-integer bond order.
(li) An O2 ion that is paramagnetic and that has an integer bond order.
(ili) An O2 ion that is diamagnetic and that has a bond order of 3.
Clearly show the charge on your ion, label all valence molecular orbitals, and show the corresponding electrons in their orbitals. Full calculations for bond orders must be included.
b) Using only the valence electron molecular orbital diagram for O2, is a
ground state diamagnetic ion with a bond order of 2 possible? Write one or twosentences to explain why or why not.

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