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Use the wedge/hash bond tools to indicate stereochenmistry where it exists. • You do not have to explicitly draw H atoms. • Use “flat" representations of rings, not chairs, in your drawing. Most stable Least stable P. aste P. opy aste орy CH3 CH3 H;C, H3C, OH HO, ČH3 ČH3

Use the wedge/hash bond tools to indicate stereochenmistry where it exists. • You do not have to explicitly draw H atoms. • Use “flat" representations of rings, not chairs, in your drawing. Most stable Least stable P. aste P. opy aste орy CH3 CH3 H;C, H3C, OH HO, ČH3 ČH3

Organic Chemistry
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter2: Alkanes And Cycloalkanes
Section: Chapter Questions
Problem 2.49P: Use your answers from Problem 2.48 to complete the table showing correlations between cis,trans and...
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Is this right, can you check it pls. both are together/connected

Use the wedge/hash bond tools to indicate stereochemistry where it exists. • You do not have to explicitly draw H atoms. • Use “flat" representations of rings, not chairs, in your drawing. Most stable Least stable C P. C P. opy aste opy aste CH3 CH3 H3C, H;C OH OH CH3 ChemDoodle" ChemDoodle"
Transcribed Image Text:Use the wedge/hash bond tools to indicate stereochemistry where it exists. • You do not have to explicitly draw H atoms. • Use “flat" representations of rings, not chairs, in your drawing. Most stable Least stable C P. C P. opy aste opy aste CH3 CH3 H3C, H;C OH OH CH3 ChemDoodle" ChemDoodle"
CH3 5 H3C. `OH ČH3 3-isopropyl-5-methylcyclohexanol There are four cis,trans isomers for 3-isopropyl-5-methylcyclohexanol, where the cis,trans designations of the substituents are made relative to the OH group: • up, up, up (cis,cis) • up, up, down (cis,trans) • up, down, down (trans,cis) • up, down, up (trans,trans) Consider the most stable chair for each of these isomers, and then draw the most stable and least stable isomer based on a comparison of the best chair for each one. • To simplify matters, consider only axial vs equatorial energies of the groups (i.e. do not worry about the interactions between the groups, which in reality is also important). • Use the wedge/hash bond tools to indicate stereochemistry where it exists. You do not have to explicitly draw H atoms. Use "flat" representations of rings, not chairs, in your drawing. Most stable Least stable Previous Next
Transcribed Image Text:CH3 5 H3C. `OH ČH3 3-isopropyl-5-methylcyclohexanol There are four cis,trans isomers for 3-isopropyl-5-methylcyclohexanol, where the cis,trans designations of the substituents are made relative to the OH group: • up, up, up (cis,cis) • up, up, down (cis,trans) • up, down, down (trans,cis) • up, down, up (trans,trans) Consider the most stable chair for each of these isomers, and then draw the most stable and least stable isomer based on a comparison of the best chair for each one. • To simplify matters, consider only axial vs equatorial energies of the groups (i.e. do not worry about the interactions between the groups, which in reality is also important). • Use the wedge/hash bond tools to indicate stereochemistry where it exists. You do not have to explicitly draw H atoms. Use "flat" representations of rings, not chairs, in your drawing. Most stable Least stable Previous Next
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