Fine structure and hyperfine structure of atom with some example , in detail?

Q: Use ligand group orbital approach to describe the bonding in [CO3] 2- . Include schematic…

A: Carbonates [CO3] 2-are polyatomic ligands. They are found to bind to two or three metals…

Q: Answer the following questions for square planar metal complexes ML4 (point group D4h): 1) determine…

A: Solution                                Given that  Square planer metal complexes ML4 Draw orbitals…

Q: a) Show the molecular orbital energy level diagram for o and t interaction of the orbitals in…

A: The detailed answer is attached below.

Q: Draw combinations of orbitals by using all three p orbitals of atom A and all five d orbitals of…

A: The region in the three-dimensional space of an atom and it has a greater probability of finding an…

Q: Explaining bond and magnetic properties with MO theory

A: ANSWER IS

Q: 10.26. For a trigonal prismatic complex, [TiL,], Table 7.7 indicates that the d2 orbital is at an…

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Q: ccording to the graph below, The ratio for One Metal is to how many LIGAND? ( Write a whole number)

A: In the given spectrometric titration graph: On fitting the graph into linear regression,…

Q: Some different views of an octahedral symmetry metal com

A: There are two types of ligand π acceptor or π acid ligand and sigma donar ya sigma base ligand. The…

Q: For the ground state terms of the d4 and d7 electronic configurations, determine the splitting of…

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Q: Consider a d8 compound (like Pt(II)). What is more likely to form a 4-coordinate or a 6-coordinate…

A: Valence Bond Theory (VBT) Crystal Field Theory (CFT) Considers formation of covalent bonds…

Q: About the special type of hybridization involved in complexation (all are correct except Select one:…

A: In different type of hybridization, different type of structures of complexes or coordination…

Q: b. Will vo2+ disproportionate or will V3. and VO2 comproportionate to form V02+ under acidic…

A: Under acidic condition V+3 is most stable Under basic condition V2O3 is most stable

Q: A palladium complex formed from a solution containingbromide ion and pyridine, C5H5N (a good…

A: Let’s suppose the Total mass of the product is 100 gm, then the mass of bromine is 37.6 gm, carbon…

Q: Draw the d Orbital Energy Diagrams for Weak (1st pic) and Strong Field (2nd pic) Cases. Include the…

A: Ligands which are donar are weak field ligand and donars that accept electrons are strong field…

Q: Distinguish between pi (π) and delta (δ) bonding molecular orbital (MO) using the symmetry criteria.…

A: There are different types of bonding between atoms or groups in molecules. Molecular orbitals are…

Q: Show the splitting of f orbitals with diagram, with detailed explanation. Also draw eachf orbital

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Q: BH3 exist as a dimer, also known as diborane, while BF3 is monomeric. Explain?

A: BH3   There are only six electrons around Boron.  So, we can say that BH3 is electron deficient…

Q: Why are these bravais lattices the same? B-monoclinic and primitive (P)-monoclinic (if b is the…

A: There are several ways to describe a crystalline plane. The most fundamental description is known as…

Q: The major component of household bleach is sodium hypochlorite. In South Africa, bleaching solution…

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Q: If there is a node in between two atoms in a transition state, is there a bonding or an anti-bonding…

A: Given information,       There is a node in between two atoms in a transition state.

Q: The hypofluoride ion, OF", can be observed with difficulty. Prepare a molecular orbital energy level…

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Q: А. В. b. Now consider the two molecules A. and B. Note that A. is a dianion and B. is a neutral…

A: This is the concept of aromaticity.

Q: Draw the Lewis structures and molecular orbital (MO) diagrams for CO and CN and comment on both the…

A: In lewis dot structure molecules or compounds are represented by bonding and non bonding electrons…

Q: Which d orbital on M is capable of having a bonding interaction with the ligand group orbital shown?

A: Ligands are the chemical species which have the ability to donate electron pairs.  Metals accept…

Q: Which of the following statements is true regarding the T molecular orbitals of benzene? All six…

A: In the first question, we will see which statement is true about molecular orbital for Benzene. You…

Q: Q1: give me concept terms for the following Briefly Germanium , forbidden gap , ev

A: The answer for first question is given below. Kindly repost the other questions as separate one. 1)…

Q: Construct molecular orbital energy level diagrams for O2 and BO. Comment on any differences in the…

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Q: Based on the shapes of p and d orbitals and the necessary match of symmetry, please predict and…

A: Atom A orbitals - p Atom B orbitals - d We have to draw the possible bonding interactions between A…

Q: Which of the following depictions of a ligand group orbital would have the correct symmetry to form…

A: The Ligand Group Orbital with t2 bonding character that has the correct symmetry with a 2pz orbital…

Q: Which of Au(NO3) and AuI would be expected to be more reactive? Explain your reasoning

A: Following salt is more reactive according to electrochemical series.

Q: What are the applications or importance of tris (butadiene) molybdenum?

A: Since you have asked multiple questions, we will solve the first one for you. For remaining…

Q: Draw a molecular orbital diagram for NF and calculate the bond order. Also, comment on its magnetic…

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Q: Draw a complete molecular orbital diagram for 1,3,5,7-octatetraene including: Labeled y-axis. MO…

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Q: What type of compound would display unpaired electrons in the molecular orbital diagram?

A: Paramagnetic compounds have unpaired electrons.

Q: cyclobutadiene is very unsatble, why metal complex are stable? (use mo structure to explain)

A: Cyclobutadiene is very unstable hydrocarbon as it is anti-aromatic compound. It has four pi…

Q: Explain the Simonini reaction with example.

A: Simonini reaction: The synthesis of aliphatic ester from two equivalents of silver carboxylate and…

Q: Explain when is σ- and π-notation used, and when is a-, e- and t-notation used in MO energy level…

A: MO diagram is a qualitative descriptive tool explaining chemical bonding in molecules in terms of…

Q: Which hybridization(s) is/are suitable to form a metal complex? (You can select more than one option…

A: Hybridization which are suitable for metal complex formation are sp, sp2, sp3 , dsp3 . Let's see by…

Q: (a) What coordination geometries could [AuI4]− take and how might it differ from the [AuCl4]− ion?

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Q: ow will the various d and p orbitals bond to give bonding and anti bonding molecular orbitals. Can…

A: When atomic orbitals combine, molecular orbitals are formed. When atomic orbitals combine in the…

Q: Explain when sigma(-) and pie- notation used, and when is a-, e- and t-notation used in Mo energy…

A: The arrangement of molecular orbitals of increasing the energy level by the linear combination…

Q: (a)Complex forming agents can be used to determine hardness of water how? Explain with the help of…

A: Solution: We know the hardness of water is due to presence of Ca2+ and Mg2+ ion. So these ions are…

Q: 1. Use specific examples, convincingly explain, and using your own words the differ- ence between…

A: Configurational isomers are type of stereoisomers which can not be converted to one…

Quantum Mechanical Treatment of the Valence Bond Theory

Quantum mechanical treatment of valence bond theory refers to the relationship established between the quantum mechanical theory and the valence bond theory to describe the chemical bonding in a particular molecule.