Using reaction free energy to predict equilibrium composition D 1/5 Consider the following equilibrium: 2NO (g)+ Cl, (g) 2NOCI (g) AG" = - 41. kJ Now suppose a reaction vessel is filled with 2.34 atm of nitrogen monoxide (NO) and 9.71 atm of nitrosyl chloride (NOCI) at 426. Answer the following questions about this system: rise Under these conditions, will the pressure of NO tend to rise or fall? O fall Is it possible to reverse this tendency by adding Cl,? In other words, if you said the pressure of NO will tend to rise, can that yes be changed to a tendency to fall by adding Cl,? Similarly, if you said the no pressure of NO will tend to fall, can that be changed to a tendency to rise by adding Cl,? If you said the tendency can be reversed in the second question, calculate the minimum pressure of CI, needed to reverse it. atm Round your answer to 2 significant digits.

Chemistry for Engineering Students
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Chapter10: Entropy And The Second Law Of Thermodynamics
Section: Chapter Questions
Problem 10.80PAE
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O ENTROPY AND FREE ENERGY
Using reaction free energy to predict equilibrium composition
1/5
Consider the following equilibrium:
2NO (g)+ Cl, (g)
2NOCI (g)
AG" = - 41. kJ
Now suppose a reaction vessel is filled with 2.34 atm of nitrogen monoxide (NO) and 9.71 atm of nitrosyl chloride (NOCI) at 426. °C.
Answer the following questions about this system:
rise
Under these conditions, will the pressure of NO tend to rise or fall?
O fall
Is it possible to reverse this tendency by adding CI,?
In other words, if you said the pressure of NO will tend to rise, can that
yes
be changed to a tendency to fall by adding Cl,? Similarly, if you said the
12?
no
pressure of NO will tend to fall, can that be changed to a tendency to rise
by adding Cl2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of CI, needed to reverse it.
|| atm
Round your answer to 2 significant digits.
II
Transcribed Image Text:O ENTROPY AND FREE ENERGY Using reaction free energy to predict equilibrium composition 1/5 Consider the following equilibrium: 2NO (g)+ Cl, (g) 2NOCI (g) AG" = - 41. kJ Now suppose a reaction vessel is filled with 2.34 atm of nitrogen monoxide (NO) and 9.71 atm of nitrosyl chloride (NOCI) at 426. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NO tend to rise or fall? O fall Is it possible to reverse this tendency by adding CI,? In other words, if you said the pressure of NO will tend to rise, can that yes be changed to a tendency to fall by adding Cl,? Similarly, if you said the 12? no pressure of NO will tend to fall, can that be changed to a tendency to rise by adding Cl2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of CI, needed to reverse it. || atm Round your answer to 2 significant digits. II
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