Using the following atomic orbital pictures and radial probability distribution plots: a) Identify atomic orbital #1. Indicate the number of radial and angular nodes. b) Identify atomic orbital # 2. Indicate the number of radial and angular nodes. c) What type of molecular orbital (o, n, or no interaction) will be formed when these orbitals approach each other along the x axis? Describe the orbital overlap if applicable. Assume that the atomic orbitals are at appropriate energy levels to mix. Atomic Orbital #1 R 007 0.06 005 004 003 0.02 001 10 20 40 50 r (ao) Atomic Orbital #2 R 012 01 0.00 04 002 15 r (a.)
Formal Charges
Formal charges have an important role in organic chemistry since this concept helps us to know whether an atom in a molecule is neutral/bears a positive or negative charge. Even if some molecules are neutral, the atoms within that molecule need not be neutral atoms.
Polarity Of Water
In simple chemical terms, polarity refers to the separation of charges in a chemical species leading into formation of two polar ends which are positively charged end and negatively charged end. Polarity in any molecule occurs due to the differences in the electronegativities of the bonded atoms. Water, as we all know has two hydrogen atoms bonded to an oxygen atom. As oxygen is more electronegative than hydrogen thus, there exists polarity in the bonds which is why water is known as a polar solvent.
Valence Bond Theory Vbt
Valence bond theory (VBT) in simple terms explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. It gives a quantum mechanical approach to the formation of covalent bonds with the help of wavefunctions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.
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