Using the pictures of the trials given, I need help answering this question. 1.From your knowledge of X and Y in the equation (as well as the rate in a given experiment from your graph) calculate k from your data. Rate= K[I^-]^x [S2O8^2-]^y

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.29QAP
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Using the pictures of the trials given, I need help answering this question.

1.From your knowledge of X and Y in the equation (as well as the rate in a given experiment from your graph) calculate k from your data.
Rate= K[I^-]^x [S2O8^2-]^y

Total moles of
2-
Time (s) between
appearances of color
Cumulative times (s)
S₂O3²- consumed
147 (5)
2.0×10-4
197 (5)
180 (5)
32 7 (5)
4.0×10-4
-203 (5)
530 (5)
6.0×10-4
199 (5)
724 (5)
8.0×10-4
7
927 (5)
10.×10-4
6
-207 (5)
1134 (5)
12×10-4
7
266 (5)
1400 (5)
14×10-4
Solution 4. Initial [S₂Og2] = 0.10 M; initial [I] = 0.025 M. Time experiment started o
Total moles of
Time (s) between
appearances of color
Aliquot no.
2-
Cumulative times (s)
$₂O² consumed
1
2.0×10-4
2
4.0×10-4 xast kont
3
6.0×10-4
4
8.0×10-4
5
10.x10 4
12×10-4
14×10-4
Calculations
1. Rate of reaction, A[S₂O3²-]/At, as calculated from graphs (that is, from slopes of lines):
2-
-6
Solution 1 4,7 xlo
Solution 2,0XS
Solution 3 ₁0X15
Solution 4
2. What effect does doubling the concentration of I have on the rate of this reaction?
about Jouble Decreases by about 2
3. What effect does changing the [S₂O82] have on the reaction?
Increases by about 2
4. Write the rate law for this reaction that is consistent with your data.
2
Rate = K[t'] [5₂0]
Aliquot no.
1
2
67
3
4
5
Transcribed Image Text:Total moles of 2- Time (s) between appearances of color Cumulative times (s) S₂O3²- consumed 147 (5) 2.0×10-4 197 (5) 180 (5) 32 7 (5) 4.0×10-4 -203 (5) 530 (5) 6.0×10-4 199 (5) 724 (5) 8.0×10-4 7 927 (5) 10.×10-4 6 -207 (5) 1134 (5) 12×10-4 7 266 (5) 1400 (5) 14×10-4 Solution 4. Initial [S₂Og2] = 0.10 M; initial [I] = 0.025 M. Time experiment started o Total moles of Time (s) between appearances of color Aliquot no. 2- Cumulative times (s) $₂O² consumed 1 2.0×10-4 2 4.0×10-4 xast kont 3 6.0×10-4 4 8.0×10-4 5 10.x10 4 12×10-4 14×10-4 Calculations 1. Rate of reaction, A[S₂O3²-]/At, as calculated from graphs (that is, from slopes of lines): 2- -6 Solution 1 4,7 xlo Solution 2,0XS Solution 3 ₁0X15 Solution 4 2. What effect does doubling the concentration of I have on the rate of this reaction? about Jouble Decreases by about 2 3. What effect does changing the [S₂O82] have on the reaction? Increases by about 2 4. Write the rate law for this reaction that is consistent with your data. 2 Rate = K[t'] [5₂0] Aliquot no. 1 2 67 3 4 5
The color of the starch 1₂ complex is dark bive
Kinetics Experiment
ion 1. Initial [S₂082] = 0.050 M; initial [I] = 0.050 M. Time experiment started
Total moles of
Time (s) between
appearances of color
S₂O8 consumed
ot no.
Cumulative times (s)
1
349 (5))
349 (5)
2.0×104
397 (s).
4.0×10-4
746 (5)
3
413 (s).
6.0×10-4
159 (5)
4
457 (5)
1616 (5) Fe
8.0×10-4
438 (5)
2054 (5)
10.x10-4
491 (5)
2595 (5)
12x104
565 (s)
3/10 (5)
14×10-4
on 2. Initial [S₂0g2] = 0.10 M; initial [I] = 0.050 M. Time experiment started
Total moles of
2-
ot no.
Time (s) between
appearances of color
156 (s)
S₂O3²- consumed
Cumulative times (s)
156 (5)
2.0×10-4
195 (5)
351 (5)
4.0×10-4
5.99 (3)
6.0×10
- 198 (5)
-194 (5)
-197 (5)
743 (5)
8.0×10-4
9 40 (5)
10.x10-4
дод. (5)
1142 (5)
12×10-4
201 (5)
1343 (5)
14x104
ht © 2018 Pearson Education, Inc.
Transcribed Image Text:The color of the starch 1₂ complex is dark bive Kinetics Experiment ion 1. Initial [S₂082] = 0.050 M; initial [I] = 0.050 M. Time experiment started Total moles of Time (s) between appearances of color S₂O8 consumed ot no. Cumulative times (s) 1 349 (5)) 349 (5) 2.0×104 397 (s). 4.0×10-4 746 (5) 3 413 (s). 6.0×10-4 159 (5) 4 457 (5) 1616 (5) Fe 8.0×10-4 438 (5) 2054 (5) 10.x10-4 491 (5) 2595 (5) 12x104 565 (s) 3/10 (5) 14×10-4 on 2. Initial [S₂0g2] = 0.10 M; initial [I] = 0.050 M. Time experiment started Total moles of 2- ot no. Time (s) between appearances of color 156 (s) S₂O3²- consumed Cumulative times (s) 156 (5) 2.0×10-4 195 (5) 351 (5) 4.0×10-4 5.99 (3) 6.0×10 - 198 (5) -194 (5) -197 (5) 743 (5) 8.0×10-4 9 40 (5) 10.x10-4 дод. (5) 1142 (5) 12×10-4 201 (5) 1343 (5) 14x104 ht © 2018 Pearson Education, Inc.
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