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- Rings + Unsaturation --- Hydrogenation If compound A C51H81BrN5O3P3 is hydrogenated to give compound B C51H101BrN5O3P3. How many rings does compound A have? Assume that P has a valency of 5. Would the answer be 4 rings? Formula -> unsat + rings = 1+C +N/2 - H/2 - X/2Proiide a Fisher structure for (2R,3S,4S)-2-bromo-4-methyl-3-hexanol.. Draw the conformational isomers of 1-bromo-2-chloroethane by rotating C-C single bond with dihedral angel 60°
- (a) Draw the molecular orbital picture for propa-1,2-diene, H2C=C=CH2. Hint: The three-dimensional geometry is shownin the chapter. (b) Draw the MO energy diagram for propa-1,2-diene. What is the HOMO? What is the LUMO?for the following formulas drew 2 constitutional isomers and provide names in IUPAC for ypur drawingsDr@w the chair conformation and its ring-interconversion isomer of both cis and trans-I-cyclobutyl-2methylcyclohexane and rank the four structures for stability (1 = most stable to 4 = least stable; no justifications needed). & draw in your cyclohexane ring hydrogens
- 3. Which stereoisomer can obtain the least amount of conformational strain, cis- or trans-1,3-dimethylcyclohexane? What is the difference in strain energy between these two mPls help. I think it’s Same structure drawn diff Diastereomers Same but drawn differentlyIndetify the molecule that is (2S,3R)-3-chloro-2-methylbutan-1,2-ol. (A, B, C or D)
- 5. Draw the best conformation for 1-[4-(2-methyl-2-propanyl cyclohexyl] ethanone in both trans and cis form of isomer.What is the stereochemical configuration of the enantiomer of (2S, 4R)-2, 4-octanediol? (A diol is a compound with two —OH groups.)Indicate the relationship between each pair. Choose from: configurational stereoisomers,conformers, constitutional isomers, or different formulas (Each term is used at least twice.)