What are the maximum atomic and weight percentages of Cu that can be added to Au without exceeding a resistivity that is thrice that of pure gold? (Alloys are normally prepared by mixing the elements in weight. Resistivity of Au at 0°C is 20.5 nΩ m Nordheim coefficient for Cu in Au at 20°C is C = 450 nΩ m. Resistivity of Au at 20°C, using α0 = 1/242 K-1 )

What are the maximum atomic and weight percentages of Cu that can be added to Au without exceeding a resistivity that is thrice that of pure gold? (Alloys are normally prepared by mixing the elements in weight. Resistivity of Au at 0°C is 20.5 nΩ m Nordheim coefficient for Cu in Au at 20°C is C = 450 nΩ m. Resistivity of Au at 20°C, using α0 = 1/242 K-1 )

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter17: Electrochemistry

Section: Chapter Questions

Problem 48P

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1.065 g of stainless steel was dissolved in hydrochloric acid (chromium as Cr 3+ ) and diluted to 500.0 ml. A 50.00 ml sample was passed through a Walden reducer, where only iron is reduced (Fe3+ + e-  Fe2+), and titrated with 0.01920 M KMnO4 solution, which consumed 13.72 ml. A 100.0 ml sample was passed through a Jones reducer (Cr3+ + e-  Cr2+ and Fe3+ + e-  Fe2+) into 50.00 ml of a 0.1000 M Fe3+ solution. The resulting solution was titrated with 0.01920 M KMnO4 solution and 36.43 ml was consumed. Calculate the Fe and Cr concentrations of the sample in weight percent.
(a) What is the percentage of MnO2 in a pyrolusite ore if a sample weighing 0.4000 g is treated with a 0.6000 g of pure H2C2O4.2H20 and dilute H2SO4 and after reduction has taken place (MnO2 + H2C2O4 + 2H+ Mn2+ + 2CO2 + 2H2O), the excess oxalic acid requires 26.26 mL of 0.1000 N KMNO4 for titration? (b) If pure As2O3 were used instead of oxalic acid, how many grams would be required in order for the other numerical data to remain the same?
Resistivity measurements at 300 K show that an annealed metal single crystal has amonovacancy concentration CV = 10-9. When the same crystal is quenched from a hightemperature, the measurements indicate CV = 2x10-3. Calculate the temperature of thequench [Take Hf = 51.4 kJ/mol and R = 8.314 J/mol.K]. State any assumption involved. (5)(b) Explain why the esistivity of a metal is expected to be found more at room temperature after quenching. Hint: Use Matthiessen’s rule (find out by self-studying and cite thesource.)
9 The pyrite (iron sulfide) roasting process is carried out following the next reaction [FeS2 (s) + O2 (g)]25°C → [Fe2O3 (s) + SO2(g)] 900 °C a) Determine the enthalpy balance for the reaction as stated in the reaction shown b) Determine the enthalpy balance using air with 10% excess and preheated to 500°C
The electrical resistance of a column of 0.05 mol L-1 NaOH solution of diameter 1 cm and length 50 cm is 5.55 X 103 ohm. Calculate its resistivity, conductivity and molar conductivity.
2. Write the two defect reactions for the solution of Nb2O5 into TiO23. Calculate the lattice parameter and crystal density for ZrO2 containing 10 mole% Y2O34. Calculate the lattice parameter and crystal density for MgO containing 0.1 mole% CaO5. Calculate the lattice parameter and crystal density for MgO containing 0.05 mol% Al2O3
A 0.9352g sample of ore containing Fe³+, Al³+ and Sr²+ was dissolved and made up to 500.00 mL. The analysis of metals was performed using complexation volumetry. Initially, an aliquot of 50.00 mL had its pH adjusted to 1.0 and titrated with a standard 0.03145 mol/L EDTA solution, requiring 6.95 mL to reach the end point. Subsequently, another 25.00 mL aliquot was buffered at pH=5 and titrated with the same EDTA solution, requiring 6.24 mL to reach the end point. Finally, a third aliquot of 25.00 mL was titrated at pH=11, requiring 11.10 mL of the same EDTA solution to complete the titration. Given the molar masses: Fe=55.845 g/mol; Al-26.982 g/mol and Sr-87.620 g/mol. a) Determine the percentage of each of the metals in the sample. b) Explain why the change in pH allows the determination of the three ions in this sample.
Copper is produced from chalcopyrite concentrate from a mixed type ore containing 1.2% CuFeS2 (chalcopyrite) and 6% Cu3 (CO3) 2 (OH) 2 (azurite) by sulfating roasting leaching method. 4 tons of chalcopyrite concentrate is roasted daily. If it is assumed that the amount of iron in the solution is 20% under the same conditions, how much copper is produced in 1 day?
To analyze the amount of iron (Fe; Mw = 55.85 g/mol) contained in an ore sample, the sample was digested with acid and diluted to 50 mL with water. This solution was then treated with 25.00 mL of 0.2922 M EDTA. The excess EDTA was back titrated with 6.47 mL of 0.0843 M Zn2+ to reach the equivalence point. How many grams of Fe contained in the ore sample?
If 2.376 g of steel gave 0.402 g of Ni(DMG)2, what is the wt% Ni in the steel?
Given: You weigh out exactly 0.200 g of Fe(NH4)2(SO4)2·6H2O and dissolve it in the 100.00 mL volumetric flask. You then pipette 2.00 mL of this solution into the 50.00 mL volumetric flask to prepare the stock standard tris-bipyridyl-iron(II) solution. a. Calculate the molar concentration of iron(II) in this solution in the 50.00 mL volumetric flask. (The MW of Fe(NH4)2(SO4)2·6H2O is 392.14 g/mol) (answer a given the information above)
A sample of steel weighing 2.00 g is analyzed for Cr (AW 52.0). The Cr is oxidized into chromate with alkaline permanganate and the excess permanganate is destroyed. A certain volume of 0.120 M FeSO4 is added to the acid solution and the excess is titrated with 0.0220 M KMnO4, requiring 31.0 mL. If the sample contained 0.50 % Cr, what volume (in mL) of FeSO4 was added?