6. What are the differences between these complexes [Co(NH3)6]Cl3 , [Co(H20)6]Cl2, (Base your answer on their colours, geometry and magnetic properties)? Show the field type and how this will affect the splitting in the d-orbital according to CFT?

Q: 7) If you were to use a ligand L that was a stronger field ligand than NH3, what color would you…

A: Step : 1             The required answer is follows as :

Q: answer

A:

Q: Oxyhemoglobin, with an O2 bound to iron, is a low-spin Fe(II) complex; deoxyhemoglobin, without the…

A: Hemoglobin is a protein in body that acts as carrier of oxygen in body. When it combines with oxygen…

Q: By using the Tanabe-Sugano diagram, explain why there are only two absorption bands in the UV-Vis…

A: Tanabe-Sugano diagrams are used to explain the electronic spectra of the different compounds.

Q: 2. Why can an organometallic complex perform the reactions such as insertion where normal…

A: 1) organometallic complexes which involves the bond formation between carbon and hydrogen atom…

Q: 7 How would you expect the molecule 1,10-phenanthroline (shown below) to function as a ligand? H H H…

A:

Q: If given the choice of a complexometric titrant among the choices below, which would be the best…

A:

Q: In the preparation of some of the solutions of metal complexes, what is done to ensure that the…

A: In several metal complexes the central metal atoms are oxidised and most of them have charge on the…

Q: (a) Draw all the possible isomers of [Fe(NH3);Br3] and for each isomer clearly indicate the…

A: a) There are two possible isomers of the given compound, fac and mer. These are shown as below:…

Q: With the aid of diagrams Explain how you would apply crystal field theory to explain why the five…

A: Crystal field splitting energy is defined as energy difference between two set of orbitals.

Q: Write down the IUPAC names of the following complexes and also give stereochemistry and magnetic…

A:

Q: Which of the following is responsible for the chelate effect exhibited by multidentate ligands? a.…

A: This question is related to coordination Chemistry. Coordination complexes are the molecules in…

Q: could you please draw proposed structures for these three complexes? Ni(NCS)2(PPh3)2 NiCl2(PPh3)2…

A: Ni(NCS)2(PPh3)2 NiCl2(PPh3)2

Q: 2. (a) The v(CO) of isoelectronic series [Mn(CO).], [Cr(CO)] and [V(CO) are 2090 cm 2000cm¹ and 1860…

A: All the parts of the questions are answered properly!!

Q: 1.Show how a Fischer carbene complex can be prepared starting from Mo(CO)6 . 2.How would you explain…

A: Back donation:The carbonyl ligand that coordinated with the metal has electron rich sp orbital. The…

Q: 23.58: a,b,c

A: (a) The central metal ion in the complex K3 [FeCN6] is Fe . The K atoms are written out of the…

Q: Write the formula for a complex formed between Fe³+ and ethylenediamine (NH, CH,CH,NH, ), with a…

A: Interpretation -  To write the formula formed for a complex  between Fe3+ and ethylenediamine with…

Q: What is crystal field theory?Briefly discuss the colors of transmission Metal Complexes.

A: The Crystal Field Theory (CFT) is a model for the bonding interaction between transition metals and…

Q: The number of unpaired electrons expected for the complex ion: [Co(OH)6]3- is: Classify as…

A: 1) Given compound: CoOH63- In this cobalt is +3 oxidation state. The electronic configuration of…

Q: Explain why there is no distinction between low and high-spin arrangements for an octahedral d8…

A:

Q: A. If you are going to prepare Cu(1) solution that will have a 0.2 absorbance when complexed with…

A: To answer questions related to Cu-phenanthroline complex.

Q: How would you distinguish experimentally between the two configurations of high and low spin in d4…

A:

Q: How many bonds could each of the following chelating ligands form with a metal ion? acetylacetone…

A: Since we only answer up to 3 sub-parts, we’ll answer the first 3. Please resubmit the question and…

Q: Explain why [Cu(H2O)6]2+ reacts with 3 2,2’-bipyridine ligands but [Cu(bipy)3]2+ does not react with…

A: The compounds in which a central metal atom is available and joined with groups or molecules…

Q: 23.58: d,e

A: The central metal ion in the complex [Cr(NH3)4Br2]ClO4  is Cr. The ClO4 atoms are written out of the…

Q: In the given complex of [Fe(CO)6] having CO ligand, carbon and oxygen both having lone pair of…

A: if wae observe the carbon monoxide molecule it has a dative bond.

Q: How many unpaired electrons are in the low-spin octahedral complex [Co(CN),Jª¯? Provide your answer…

A: The no. Of unpaired electron in given complex = 1 (one).

Q: Why is pyridine referred to as a monodentate ligand?

A: The structure of pyridine is given as

Q: H2C2O4.2H2O + K2Cr2O7 → K[Cr(C2O4)2(H2O)2].2H2O What is the role of oxalate ion in this reaction…

A: Given reaction; H2C2O4.2H2O + K2Cr2O7 → K[Cr(C2O4)2(H2O)2].2H2O On balancing the equation;…

Q: 3. Considering an octahedral complex for the d system,what are the effect of T-donor and t- acceptor…

A: Pi donar Ligands produce lesser splitting energy so high spin will be favored. Pi accepting lingands…

Q: A complex of nickel ions, Ni2*, with 1,2-diaminoethane is octahedral in shape with a co-ordination…

A: Ni2+ forms an octahedral complex with1,2-diaminoethane (NH2C2H4 -NH2) with coordination 6. Since,…

Q: Write the formula for a complex formed between Ni? + and NH, with a coordination number of 5.…

A: Coordination complex is compound which contain central metal atom surrounded by non metal atoms or…

Q: The values for lmax for complex A and B are 512 nm and 650 nm respectively.  A has the structure…

A: 1)

Q: For each of the following metals, write the electronic configuration of the atom and its 3+ ion: (a)…

A:

Q: Write the balanced net ionic equation for the reaction of Fe3+ and NaF. Explain, in your own words,…

A: The net ionic equation for the reaction of Fe3+ and NaF is, Fe3+(aq) + 6NaF(s)  --->…

Q: The ion [Fe(CN)6]3- has one unpaired electron, whereas[Fe(NCS)6]3- has five unpaired electrons. From…

A: The coordination complexes can be defined as the complex compounds which have coordinate linkage…

Q: (a) Draw labelled d-orbital splitting diagrams for the metal centres in [CO(OH₂)6]Cl2 and…

A:

Q: Write the IUPAC name of the complex [CoBr2(en)2]+. (b) What type of isomerism is shown by the…

A: Since you have posted multiple questions, we will solve only first question for you. If you want any…

Q: Explain why there is no distinction between low and high-spin arrangements for an octahedral d8…

A:

Q: 1) What role do the protons play in the transformation of [(SALEN)VO] to [(SALEN)Cl2]?  --- Consider…

A: Protons in the transformation of (SALEN)VO to (SALEN)Cl2:The conjugate base of “salen ligand” which…

Q: Part A How many unpaired electrons are in the d orbitals of an octahedral complex of Ru3+  assuming…

A: In strong field, electrons enter the eg orbitals only when t2g orbitals are completely filled.

Q: Using crystal field theory, draw an electron box energy level diagram for the valence d orbitals on…

A:

Q: [Mn(H2O)6]?* complex has an extremely pale color, attributable to transitions which are formally…

A:

Q: The complex [Fe(CO)6]+2 exhibits π-acceptor behavior. Using ligand field theory, draw the molecular…

A: Ligand field theory is the theory which includes both the ionic and covalent bonding of the…

Q: Why are there both high-spin and low-spin octahedral com-plexes but only high-spin tetrahedral…

A:

Q: What is the CFSE of this complex? State the oxidation state and hybridisation of the metal center

A: Solved in step 2.

Q: Chemistry Please help [V(CO)6] and [V(CO)6]- are both octahedral complexes. Which has the shorter…

A: The given complexes are [V(CO)6] and [V(CO)6]- .

Q: Write the formula for a complex formed between Ag+ and NH, with a coordination number of 2. formula:…

A:

Q: What is the difference between a monodentate and a multidentate ligand? Is a chelating ligand…

A: A ligand contains 1 or more donor atoms which are coordinated to the central metal atom to form a…