What is the reason for the stoke shift for a fluorophore ?

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter6: Equilibria In Single-component Systems
Section: Chapter Questions
Problem 6.60E
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What is the reason for the stoke shift for a fluorophore ? Please shortly answer at your own words. Answer should be to the point(specific). 

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