What is the relationship between the two molecules shown below?A) enantiomersHОнОнB) diastereomersHH.-CH3C) conformational isomersН.H HHD) constitutional isomersE) identical

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Answered: What is the relationship between the…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter6: Alkanes & Alkenes

Section: Chapter Questions

Problem 37CTQ: Indicate the relationship between each pair. Choose from: configurational stereoisomers,conformers,...

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a model of cyclohexane in a chair conformation, and explain why the names “axial” and“equatorial’ are appropriate.
Fill in the blanks: cis-1,3-Dimethylcyclohexane has two different chair conformations: one withboth methyl groups in __________ positions and one with both methyl groups in ____________ positions.
Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This group is called an ethyl group and can be considered a sphere about twice the sizeof a methyl group. Draw the following Newman projections sighting down the C1C2 bond... a. The lowest potential energy conformation. b. The highest potential energy staggered conformation.
The diaxial conformation of cis-1, 3-dimethylcyclohexane is approximately 23 kJ/mol (5.4 kcal/mol) less stable than the diequatorial conformation. Draw the two possible chair conformations, and suggest a reason for the large energy difference.
1) Are the molecules A and B... conformational isomers? Diastereomers? Enantiomers? Position isomers? Non-related? 2) What about the molecules B and C? 3) What about the molecules C and D?
Take a look at the butane conformers below. Identify: (a)Which is an anti conformation in Newman? (b)Which is a Gauche conformation? (c)Which is the more stable Sawhorse conformer? (d)Which has the same potential energy/strain with ALS?
Draw the highest and lowest energy conformations. In cases where two or three conformations are degenerate, choose only one as your anwser. Use Pr, Me, H, Et in the structures.
The diaxial conformation of cis- 1,3-dimethylcyclohexane is approximately 23kl/mol (5.4 kcal/mol) less stable than the diequatorial conformation. Draw thetwo possible chair conformations, and suggest a reason for the large energydifference.
Draw the Newman projections of the three p0ssible staggered c0nf0rmati0ns 0f 2,3-dimethylbutane, viewed through the C2—C3 b0nd. What are the relative energies 0f each conformation?
Which chair conformation is more stable? Is it the right because bromine has a larger mass than a methyl group? Or is it the left because the methyl group has three hydrogens stemming from the carbon and is therefore ‘bulkier?’
For each compound below, draw two chair conformations and identify which of them is more stable. Briefly explain (not more than one sentence) your choice.
a) Enter the name of the following compound. B) Write down all the chair conformations. c) Which conformation is the most stable and explain why. d) Which conformation is the least stable and explain why.

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What is the relationship between the two molecules shown below? A) enantiomers B) diastereomers H H Он H он H- H. C) conformational isomers CH3 H H D) constitutional isomers E) identical