Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 6, Problem 4E

Consider the molecule 1-bromo-2-methylbutane. C 3 and C 4 should be drawn as Et as in theexample. This group is called an ethyl group and can be considered a sphere about twice the sizeof a methyl group. Draw the following Newman projections sighting down the C 1 C 2 bond...
Chapter 6, Problem 4E, Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This a. The lowest potential energy conformation.
b. The highest potential energy staggered conformation.

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For the 1,2-dichlorocyclohexane stereoisomers, which conformation of the trans stereoisomer has the lower energy, the diaxial or the diequatorial conformer? Which isomer and conformation of the three you built has the lowest energy? E of all the isomers of 1,2-dichlorocyclohexane. Explain the differences in energy, i.e., identify the sources of strain in the conformations you built. Show the sources of strain in a drawing.
Create a conformational analysis using the molecule in the picture. Follow the instruction in the picture when you transform the molecule into its Newman projection. Which conformer is the most unstable? Explain.
For 1,2-dichloroethane: ( Q.) Which eclipsed conformation(s) has (have) the lowest energy? Which has (have) the highest energy?

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Organic Chemistry: A Guided Inquiry

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