When do you use NBS vs. Br2 in bromination? I know you can use Br2 and heat for free radical "markovnikov" addition, and you can use Br2 and peroxide for anti-Markovnikov addition, but then what is the purpose of NBS?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter23: Addition To A Carbonyl
Section: Chapter Questions
Problem 42E
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When do you use NBS vs. Br2 in bromination? I know you can use Br2 and heat for free radical "markovnikov" addition, and you can use Br2 and peroxide for anti-Markovnikov addition, but then what is the purpose of NBS?

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