When the Ti3+ ion is complexed by ligands X (a neutral molecule) and Y" (an anion) it gives octahedral species of the type [TIX)6)3+ and [Ti(Y)6)³, respectively, which have two different colours. The complex containing ligand X shows a single absorbance in the visible region with a peak maximum at 520 nm, while that containing Y has a peak maximum at 580 nm. Which of the two ligands produces the higher crystal field splitting energy (CFSE) for Cu2+? O a. The crystal field splitting is not caused by the ligand as one complex is a cation and one is an anion O b. The CFSES for the two complexes are the same O. Ligand X produces the higher CFSE O d. Ligand Y produces the higher CFSE

Chemistry: The Molecular Science
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ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
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When the Ti3+ ion is complexed by ligands X (a neutral molecule) and Y" (an anion) it gives octahedral species of the type
[TIX)6)3+ and [Ti(Y)6)³, respectively, which have two different colours. The complex containing ligand X shows a single
absorbance in the visible region with a peak maximum at 520 nm, while that containing Y has a peak maximum at 580 nm.
Which of the two ligands produces the higher crystal field splitting energy (CFSE) for Cu2+?
O a. The crystal field splitting is not caused by the ligand as one complex is a cation and one is an anion
O b. The CFSES for the two complexes are the same
O. Ligand X produces the higher CFSE
O d. Ligand Y produces the higher CFSE
Transcribed Image Text:When the Ti3+ ion is complexed by ligands X (a neutral molecule) and Y" (an anion) it gives octahedral species of the type [TIX)6)3+ and [Ti(Y)6)³, respectively, which have two different colours. The complex containing ligand X shows a single absorbance in the visible region with a peak maximum at 520 nm, while that containing Y has a peak maximum at 580 nm. Which of the two ligands produces the higher crystal field splitting energy (CFSE) for Cu2+? O a. The crystal field splitting is not caused by the ligand as one complex is a cation and one is an anion O b. The CFSES for the two complexes are the same O. Ligand X produces the higher CFSE O d. Ligand Y produces the higher CFSE
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