Which alkene will be formed (E or Z) in each of these elimination reactions? Explain your answer mechanistically. Ph3P+ base x= R₂ ÕH R₁ Me Si R₁ R₂ ÕH base ? ? PhSO2 R₁ Me Si R₁ R₂ ŌAC ÕH Na/Hg acid ? ?

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 29AP: Propose a pericyclic mechanism to account for the following transformation:
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Which alkene will be formed (E or Z) in each of these elimination reactions? Explain
your answer mechanistically.
Ph3P+
base
X=
R₂
ÕH
Me Si
ÕH
base
?
?
PhSO2
R₁
Me Si
R₂
ŎAc
ÕH
Na/Hg
acid
?
?
Transcribed Image Text:Which alkene will be formed (E or Z) in each of these elimination reactions? Explain your answer mechanistically. Ph3P+ base X= R₂ ÕH Me Si ÕH base ? ? PhSO2 R₁ Me Si R₂ ŎAc ÕH Na/Hg acid ? ?
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