Question 1Which ion would you expect to have the largest crystal field splitting, A?strong weakCN,CO NO₂ en NH3 H₂O ox OH F SCN,CI Br 1Relative ligand field strengthsO [Co(H20)6]2+O Not enough information to determineO [COC14]2-© [Co[NH3)6]2+Question 2Which ion would you expect to have the largest crystal field splitting, A?O[Rh(H20)6]3+O[Rh(H20)6]2+Rh(CN)613-O [Rh(CN)6]4- DQuestion 5What happens during reductive elimination?the product is oxidized and the metal is releasedthe product is released and the metal is reducedthe product is released and the metal is oxidizedO the product is reduced and the metal is oxidized

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Which ion would you expect to have the largest crystal field splitting, A? strong weak CN,CO NO₂ en NH3 H₂O ox OH F SCN,CI Br I Relative ligand field strengths O [Co(H20)6]2+ O Not enough information to determine O [CoC14]2- © [Co[NH3]6]2+

Which ion would you expect to have the largest crystal field splitting, A? strong weak CN,CO NO₂ en NH3 H₂O ox OH F SCN,CI Br I Relative ligand field strengths O [Co(H20)6]2+ O Not enough information to determine O [CoC14]2- © [Co[NH3]6]2+

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter20: Transition Metals And Coordination Chemistry

Section: Chapter Questions

Problem 97CP

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Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

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Experiments show that K4[Cr(CN)6] is paramagnetic and has two unpaired electrons. The related complex K4[Cr(SCN)6] is paramagnetic and has four unpaired electrons. Account for the magnetism of each compound using the ligand field model. Predict where the SCN ion occurs in the spectro-chemical series relative to CN.
Trimethylphosphine, P(CH3)3, can act as a ligand by donating the lone pair of electrons on the phosphorus atom. If trimethylphosphine is added to a solution of nickel(Il) chloride in acetone, a blue compound that has a molecular mass of approximately 270 g and contains 21.5% Ni, 26.0% Cl, and 52.5% P(CH3)3 can be isolated. This blue compound does not have any isomeric forms. What are the geometry and molecular formula of the blue compound?
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