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- Draw the structure of two alkenes that would yield 1‑methylcyclohexanol when treated with Hg(OAc)2Hg(OAc)2 in water, then NaBH4NaBH4Consider a reaction where cis-but-2-ene is treated with a peroxy acid followed by OH- /H20. Draw the structure of one product that is formed in the reaction, including correct stereochemistry.Which structure will not yield cis- or trans- isomers after a reaction with H2/Lindlar catalyst or Na/NH3?
- Name (including E/Z stereochemistry) the five alkenes that can produce 3-bromo-3-methylhexane on reaction with HBr. Draw the skeletal structure of each molecule.1. Ethylene glycol, a major component of antifreeze, becomes especially poisonous when it is oxidized by the liver. Draw two oxidation products that could be derived from ethylene glycol. 2.When 2-methyl-1-butanol is dehydrated in an acid medi- um to an alkene, it yelds mainly 2-methyl-2-butene rather than 2-methyl-1-butene. This indicates that the dehydra- tion to an alkene is at least a two-step reaction. Suggest a mechanism to explain the reaction.True or False1. The carbocation of n-propyl alcohol is more stable than the cabocation of ispropyl alcohol. 2. The C-O-C bonds in ether have a higher bond dipole than the C-O-H bond in alcohol3. When n-propyl alcohol undergoes an elimination reaction, the resulting product is an alkene
- Draw the constitutional isomer formed when the following alkenes are treated with each set of reagents: [1] H2O, H2SO4; or [2] BH3 followed by H2O2, −OH.Which of the following reagents would NOT convert the shown alcohol into the alkene a) 1) TsCl, py 2) NaOEt b) NaOEt c) concentrated H2SO4, heatBogorol A is a natural product with the potential to fight antibiotic-resistant bacteria. Shown below is an intermediate that was used in a synthesis of bogorol A. Assign the configuration of the alkene unit as either Z or E. a. Z b. E
- Which of the following statements best describes the stereospecificity of the resultingproduct of oxidation of an alkene using KmNO4? Choices:Alcohol groups are transformed into acids.Hydroxyl groups are found on the same side.Alcohol groups undergo bond rotation.Hydroxyl groups are found on opposite side.A. the products formed when an alkene reacts with these reagents: (i) H2 in the presence of Pd catalyst (ii) HClDraw the overall reaction of 1-butanol with HBr and H2SO4 to form 1-bromobutane.