Which of the following best explains why molecular compounds tend have lower melting points than ionic compounds? A) Molecular compounds are held together by covalent bonds, and ionic compounds are held together by ionic bonds. Covalent bonds tend to be weaker than ionic, so less energy is required to break covalent bonds than ionic. Thus, molecular melting points are lower

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter3: Atomic Shells And Classical Models Of Chemical Bonding
Section: Chapter Questions
Problem 33P
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Which of the following best explains why molecular compounds tend have lower melting
points than ionic compounds?
A)
Molecular compounds are held together by covalent bonds, and ionic compounds are held
together by ionic bonds. Covalent bonds tend to be weaker than ionic, so less energy is
required to break covalent bonds than ionic. Thus, molecular melting points are lower.
B)
Molecular compounds are held together by covalent bonds, and ionic compounds are held
together by ionic bonds. However, it is the noncovalent intermolecular forces that break
when molecular compounds melt, which tend to be weaker and require less energy to
break than ionic bonds. Thus, molecular melting points are lower.
C)
Molecular compounds are made only of nonmetal atoms, and ionic compounds are made of
metal and nonmetal atoms. The covalent bonds between nonmetal atoms are weaker than
they are between metal and nonmetal atoms, so less energy is needed to break nonmetal-
nonmetal bonds. Thus, molecular melting points are lower.
D)
Molecular compounds are made only of nonmetal atoms, and ionic compounds are made of
metals and nonmetals. The electronegativity difference between metals and nonmetals is
larger than between nonmetals, so there are weaker dipole-dipole forces in molecular
compounds, which need less energy to break. Thus, molecular melting points are lower.
E)
Molecular compounds are made only of nonmetal atoms, and ionic compounds are made of
metals and nonmetals. Nonmetals have smaller atomic radii than metals, so the LDFs in
molecular compounds are weaker. Thus, molecular melting points are lower. 

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