Which of the following electron distributions will be expected for (Rh(en)3]3+? Rh°:[Kr]5s²4d7 A. (t2g)^(eg² O B. (t2leg® C. (tzg^leg)° D. (t2g)?leg)4

Q: Which one of the following complexes has a spin of S = 2? A. trans-Ni(H2O)4CI2 B. [Co(CN)6]3- C.…

A: The spin of any coordination compounds depends upon the ligand field strength. A strong field ligand…

Q: Which ion would you expect to have the largest crystal field splitting, A? O[Rh(H2016]3+…

A: Reductive elimination is a sort of organometallic reaction which results in the formation of a new…

Q: For this species below, state the point group НО HO. For this species below, state the point group…

A: In chelation hard centre prefers hard donor centre. Here Sulphur is soft donor , N is less harder…

Q: Determine the d electron configurationof [Co(H2O)6]2+complex.  A) (t2g)3(eg)2 B) (t2g)4(eg)3 C)…

A: Cobalt aqua complex = [Co(H2O)]2+ Here Co is present in +2 oxidation state. Electronic configuration…

Q: On the basis of the 18-electron rule, identify the first-row transition metal for each of the…

A: We have to find the 3d metal persent in the complexes to form 18 e system

Q: Complexes of CO, CS, CSe, and CTe CE v(C-E), cm-1 Ru-C Distance, nm CO 1934 1.829 Me,N -CE CS 1238…

A: π-acceptor ligands are the ligands that donate their pair of electrons to metal vacant orbital…

Q: colors of complexes [Co(ONO)(NH3)5]CI2 and [Co(NO2)(NH3)5]C12 with theoretically expected colors is…

A: Transition metals produce colored complexes due to the presence of d-orbitals. When these metals…

Q: Find out the first row transition metals (M) for the following compounds (all of them obey 18e rule)…

A: The organometallic compounds that obey 18e rule are found to be stable. The formula to be followed:…

Q: Which of the following pairs are coordination isomers? O A. [PtCl4(H2O)2]C12 and [PtCl3(H2O)2]Cl3 O…

A: coordination isomer : When both cation and anion are complex, in a coordination compound , then the…

Q: 2. Which of the following pair of complexes will have the lowest average CO IR stretching frequency.…

A: Concept: If there are more electron donating ligands in the complex, the more electron rich the…

Q: What is the crystal field stability energy (CFSE) value for [RhMe3(PMe3)3]?

A: Given,  Complex is = [RhMe3(PMe3)3] What is the crystal field stability energy (CFSE) value for…

Q: Q5. The following isomers were obtained for a cobalt complex. How you would distinguish them with…

A: We can decide the number of CO stretching signals present in these isomeric compound based on the…

Q: In the octahedral field, dx2-v2 and d,2 are denoted as e, orbitals with the s-symmetry while dxy,…

A: In octahedral field, the molecular orbital diagram in different kind of ligand is different.…

Q: Upioad alse (a) Predict whether [Cr(H:O)]" complex is paramagnetic or diamagnetic using VBT. (b)…

A: Diamagnetic substances can be defined as the substances that contain paired electrons and do not…

Q: In which of the following cases all complexes are square planes? (27Co, 28Ni, 46Pd, 78Pt, 79Au)…

A: Coordination complexes  with coordination number 4 can be either tetrahedral or square planar.…

Q: (.. Put the correct order of v(C=0) stretching frequencies of the complexes and explain the reason.…

A: 3. In the metal carbonyls, the CO shows σ donation to the metal orbital and π* orbital accepts an…

Q: QI: Calculate the number of covalent bonds of Germanium (Ge), Z=32?, and Zn, Z-30? Q2: Explain with…

A:

Q: (c) Please illustrate the orbital overlap that describes "back-bonding" transition metal M–CO…

A: Metal carbonyls are complexes, that involves CO as the ligand. They have both σ and π character.

Q: Which one of the following complexes has a spin of S = 2? %3D A. trans-Ni(H2O)4CI2 B. [Co(CN)6]3- C.…

A: Given : Different different complexes.  To find : complex that has a spin of S =2. Solution : As we…

Q: 4) Rank the following sigma complexes in order of increasing stability. NO₂ A + H H3CO. Br B H -Br H…

A: Answer of this question :-  Sigma complex :- Sigma complex refers to an arenium ion. The suffix…

Q: For each pair of molecules below, choose the one you would predict to be more stable and briefly…

A:

Q: Magnetic moment of a first-row transition-metal complex M(H,0), is 3.9 Bohr magnetons. Identify the…

A: The complex given is [M(H2O)6 ]2+. The magnetic moment of the complex is 3.9 Since the charge of…

Q: The calculated spin only magnetic moment for Ti3+ metal ion is а. 4.91 b. 2.83 С. 1.73 d. 3.87

A: Answer:- This question is answered by using the simple concept of calculation of spin only magnetic…

Q: 13. For each of the following pairs of complexes, which one will have higher CO infrared stretching…

A: Streching frequency of C--O  depends directly on bond order of CO bond  Higher the bond order of the…

Q: C3H§M(CO); (M: transition metal) complex obey the 18 electron rules. Draw two possible ture for…

A: Transition elements are elements which have partially filled d orbitals. International Union for…

Q: The cis isomer of tetraamminedichlorocobalt(III) bromide appears red while the trans isomer appears…

A:

Q: Find out the first row transition metals (M) for the following compounds (all of them obey 18e rule)…

A: The 18 e- rule is used to predict the formula for stable metal complex. Also it can help in…

Q: Rank the following complexes from smallest to largest d-orbital splitting i) [Fe(CN)6]3- ii)…

A: The complexes given are (i) [Fe(CN)6]3−, (ii) [Fe(CN)6]4−, (iii) [Fe(Cl)6]4−, (iv) [Ru(CN)6]3−

Q: A complex of formula [M(N = CCH3)6](NO3)2, in which the M(II) ion is that of a firstrow (3d)…

A: Answer: With the help of Magnetic moment, find out the number of unpaired electrons central metal…

Q: (a) Distinguish between two ionisation isomers of [Co(NH3)5 CI]SO 4 spectroscopy. by IR

A: Can be distinguish by IR stretching Frequency.

Q: The d-electron count of the transition metal center for [((7-CSH3)Ir(CO)2(CH3)] and (Rh(PPH3),CI],…

A:

Q: Arrange these complexes in order of octahedral splitting energy, A.. Largest A. Smallest Ao Answer…

A:

Q: Explain the d-d transitions for [Ti(H2O)6]3+

A: Solution: a)for [Ti(H2O)6]3+ complex. Here first we habe to find how many electron are there in d…

Q: Q4 Explain the difference between the two complexes diamagnetic [Co(en);]3+ and paramagnetic…

A: The given two complexes are:

Q: For which member of the following pairs of complexes would A. be larger and why? i [Cr(H:O)k]* and…

A: By comparing ligand field strength and central metal ion we can decide the value of Δo for a…

Q: 5) Rank the following sigma complexes in order of increasing stability. H **$$ Br Br H NO₂ + A H Br…

A: Given:

Q: Magnetic moment of a first-row transition-metal complex M (H,O), is 3.9 Bohr magnetons. Identify the…

A:

Q: Predict the nature, including the correct special isomerisation (i.e. cis/trans) when necessary, of…

A: A question based on trans effect, which is to be accomplished.

Q: The longest wavelength transition of (CH3) 2O compound is 2520 at 184 nm. transition.Which orbitals…

A: A question to determine the orbital transition which is responsible for the longest wavelength…

Q: Calculate the total spin of this complex ion [NiCl6] 4-

A: Magnetic moment is given by √n(n+2) where n is number of unpaired electron  Cl is the weak filed…

Q: NaSH SH SH D

A: Since you have asked multiple questions, we will solve the first question for you. If you want any…

Q: 1: solutions is 1 mol dm Which of them contains the The concentration of each of the followving…

A: p orbitals have dumbbells shape.  No. Of ions = moles × NA Where NA is Avagadaro no.

Q: Which hybridization(s) is/are suitable to form a metal complex? (You can select more than one option…

A: Hybridization which are suitable for metal complex formation are sp, sp2, sp3 , dsp3 . Let's see by…

Q: (g (n' (h M(n-CSH5):(CO)(M=M bond) 3 Calculate the Total Valence Electron (TVE) and sketch the…

A: Total valence electrons of a complex is equals to the valence electron of metal (d + s electrons)…

Q: Loving to another question will save this response. 19 complex [Co(NH3)6l absorbs light at a…

A: Given,the complex [Co(NH3)6]2+ absorbs light at a wavelength 465nm. Calculate the ligand field…

Q: Example 6. Why does Mn(II) show maximum paramagnetic character amongst the bivalent ions of the…

A:

Q: H H - N - H H C- H H - N - C-H | H-C- F: (CH3)2NH CH3NH2 NH3 NF3

A: Welcome to bartleby ! We have to tell the steric number and coordination geometry of central atom

Q: (ii1.) Using your bonding dèscription from part (i.), together with the knowledge that CO ligands…

A: When a metal is bonded to a CO ligand, the metal donates the electron density it has to the CO…

Q: Example 5. Give the number of unpaired electrons in the fol- lowing: (i) Cr²+ (Z = 24) (iii) Mn²+ (Z…

A: