What is the crystal field stability energy (CFSE) value for [RhMe3(PMe3)3]?

Q: The complex [Co(NH3)6]Cl3 is yellow orange while [Co(OH2)3F3] is blue. Suggest an explanation for…

A: The colour shown by the complexes are the complementary colours of the wavelength of light absorbed.…

Q: K3[Al(C2O4)3]*3H2O is colorless?

A: The given compounds are coordination compounds. Coordination compounds are those compounds which on…

Q: Predict the d orbital splitting of [RuCl6]2- complex.

A: d-orbital is composed of five degenerate orbitals, and as the ligand approach through the axis, this…

Q: Discuss Nomenclature and Isomerism in Coordination Chemistry?

A: Nomenclature and Isomerism in Coordination Chemistry have to be discussed below.

Q: Consider an octahedral complex MA3B3. How many geometric isomers are expected for this compound?…

A: Isomerism-molecules with same molecular formula but different structural formula called as isomers…

Q: could you please draw proposed structures for these three complexes? Ni(NCS)2(PPh3)2 NiCl2(PPh3)2…

A: Ni(NCS)2(PPh3)2 NiCl2(PPh3)2

Q: (b) Give 5 properties of metal ions that will affect the structure and bonding in coordination…

A: The answer is attached below-

Q: Name the following coordination compound: K3[CrF6].

A: Coordination compounds: These are complexes that have a metal centre attached to groups of atoms.…

Q: What is the structure of CrO5 and what is Oxidation number of Cr in this compound?

A: The chemical structure of CrO5 is drawn as,

Q: Apply the concept of crystal-field theory to explain some of the interesting spectral and magnetic…

A: The Crystal Field Theory (CFT) is a theory for the bonding interaction between transition metals and…

Q: Write the IUPAC name of the following complex : [CO(NH3)6]3+

A: Given, [CO(NH3)6]3+

Q: Give formula Give inorganic nomenclature of these: 1. calcium tetrachloronickelate 2.…

A: Hi, since you have posted multiple subpart questions, we will answer the first three subparts for…

Q: How many unpaired electrons are there in a high-spin octahedral Fe2+ complex? A diagram will likely…

A: Octahedral Fe2+ complex:

Q: Suggest why the fluoride compound in which chromium has its highest oxidation state is CrF6 whereas…

A: The two compounds CrF6 and CrCl4 are given.

Q: How many electronic spectral bands for Ni2+ and Co2+ , one could be expected. Assign these…

A:

Q: which of these complexes will show geometrical isomerism: a  MA2X2 b  MA2XY c  MABCY d  All of these

A: Geometric isomerism:Two or more compounds with the same formula but are having different…

Q: Both H2O and ethylenediamine (en) have two nonbonding pairs of electrons. Why can en act as a…

A:

Q: According to the Crystal Field Theory, in an octahedral complex the energy levels of the orbitals….…

A: Concept is based on crystal field theory:

Q: What is the coordination number and geometry of lutetium(III) complex, Lu(THF)2(PhCH2)3

A:

Q: Construct a mode | of [Cr (C2 O4 Make sure are linked to donor atoms to indicate how the atorms…

A: The IUPAC name of this compound is Tris Oxalato chromium. It is a coordination compound. there is a…

Q: What is the crystal field stability energy (CFSE) value for [RhMe3(PMe3)3]

A: Crystal field stabilization energy is the energy which is released during the approach of ligand and…

Q: What is the oxidation state of molybdenum in dimolybdenum hexa(tertiary-butoxide) (Mo2(OCMe3)6), and…

A: A)To calculate the oxidation state of Molybednum in dimolybdenum hexa(tertiary-butoxide)…

Q: What is the molecular weight of bis(tetraethylammonium) tetrabromocobaltate(II) and calculate the…

A:

Q: Write the coordination number and oxidation state of Platinum in the complex [ Pt ( en ) , C1₂ ]

A:

Q: Why can the NH3 molecule serve as a ligand but the BH3 molecule cannot?

A: A ligand is an atom or group of atoms which is linked to a central metal atom or ion in a complex…

Q: The values for lmax for complex A and B are 512 nm and 650 nm respectively.  A has the structure…

A: Given S.No. Complex  Imax 1 [Co(NH3)4CO3]NO3 512 nm 2 [Co(NH3)4Cl2]Cl.  650 nm Explain the…

Q: Explain the hybrid type and geometric structure of the K3 [Cr (C204) 3] .3H2O complex with VBT.

A: oxidation number of Cr is +3  in this compound .

Q: Why is the highest oxidation state observed for CrCl4 onlythe +4 oxidation state, in contrast to the…

A: Given Why is the highest oxidation state observed for CrCl4 onlythe +4 oxidation state, in contrast…

Q: 1) In accordance to Crystal Field Theory (CFT): Explain in details the difference between [Fe(CN),]…

A:

Q: What is meant by crystal field splitting energy? On the basis of crystal field theory, write the…

A: Crystal field splitting energy: In presence of ligands , d-orbitals of central metal atom or ion…

Q: [Ni (NH3) 6] C12 What Dq is the crystal field stability energy of the complex?

A: According to crystal field theory, all the five d-orbitals of metal atoms are degenerate. But when…

Q: How many unpaired electrons do you predict for the tetrahedral [MnCl4]2- ion?

A: In the tetrahedral complexes, the three d orbitals (dxy, dyz, dxz) are higher in energy while the…

Q: Write the IUPAC name of the following coordination compound [NiCl4]2-.

A: The given compound is [NiCl4]2-. It is an anion. Thus suffix 'ate' will be used. Calculation of…

Q: Using IUPAC norms write the formulae for the following coordination compounds: (i)…

A: The formulae for given coordination compounds has to be given.

Q: Using crystal field theory, prove [NiCl4]2¯ is a tetrahedral paramagnetic complex.

A: Crystal field theory ia an electrostatic model which considers the metal-ligand bond to be ionic…

Q: Elucidate the bonding of the following complexes according to the valence-bond theory approach: (a)…

A: As there are four ligand attached to nickel so  molecule has either tetrahedral or square planar…

Q: Based on crystal field theory, please write the d-orbital energy diagrams in the Following…

A: The Crystal Field Theory (CFT) is a model for the bonding interaction between transition metals and…

Q: 4. Using crystal field theory, prove [NiCla]²- is a tetrahedral paramagnetic complex.

A: The given complex is NiCl42-, has nickel metal as the central metal atom and the ligands are four…

Q: Elucidate the bonding of the following complexes according to the valence-bond theory approach: (a)…

A: Valence bond theory is used to determine the bonding in atoms of a molecule by overlapping of their…

Q: 1. Draw two possible resonance structures for DMSO, where S is the central atom. What kind of bond…

A: 1. DMSO means dimethyl sulfoxide contains two S-Me and one S=O with one l.p. on S atom. It's…

Q: Part A How many unpaired electrons are in the d orbitals of an octahedral complex of Ru3+  assuming…

A: In strong field, electrons enter the eg orbitals only when t2g orbitals are completely filled.

Q: Estimate the crystal field stabilization energy for the octahedral ion hexaaquacobalt(III) , if the…

A: CFSE value calculation of a hexaaquacobalt complex :

Q: Estimate the crystal field stabilization energy for the octahedral ion trioxalatochromate(III) , if…

A: The question is based on concept of atomic structure. We have to calculate crystal field…

Q: why d³ and d⁸ high spin complexes are more stable than other configurations?

A: High spin complexes: According to crystal field theory, two types of complexes are formed. High spin…

Q: NO2 NO2 NO2 py-Pt-CI H3N-Pt-CI ру — Pt —NH3 NH3 ру CI А B C Show how these isomers will be…

A:

Q: One of the more famous species in coordination chemistry is the Creutz-Taube complex: 5+ (NH3);RuN…

A: (a). There is one metal ion in the complex i.e; Ru. It exhibits two different oxidation states: 1st…

Q: Discuss crystal field theory with respect to octahedral complexes. Include in your answer how the…

A: Given: CFT To Find: CFT with respect to octahedral complexes and describe properties of metal…