For this species below, state the point groupНООНFor this species below, state the point group2-OH2.CICIMn'CIÓH2CIWhich of the following ligands would be best for chelating a Cu(II) ion?HSSHH2NОННОНо

In chelation hard centre prefers hard donor centre. Here Sulphur is soft donor , N is less harder…

For this species below, state the point group НО HO. For this species below, state the point group 2- OH2 Mn CI ÓH2 Which of the following ligands would be best for chelating a Cu(II) ion? HS SH H2N ОН НО ОН

For this species below, state the point group НО HO. For this species below, state the point group 2- OH2 Mn CI ÓH2 Which of the following ligands would be best for chelating a Cu(II) ion? HS SH H2N ОН НО ОН

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter26: Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 26.30QAP

See similar textbooks

Related questions

Q: Identify the most likely second-row transition metal for each of the following: a. [M(CO);(NO)I b.…

Q: Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the…

Q: The oxalate ligand, [C:O4]²*, is a bidentate ligand and the structure of a complex ion [Fe(ox);]² is…

A: The given complex ion is a coordination complex with central metal ion (Fe3+) having 6-coordinate…

Q: Three peaks are observed at 9000, 14500, 24500 cm-1 in the [Ni(H2O)6]2+ uv-vis spectrum. What is the…

Q: The ligand-field strength also depends on the identity of the central ion, the order being Mn2+ <…

Q: NH2 H2 H,N, H2

Q: Subsequently, derive the p-bonding ligand group orbitals and draw a second qualitative molecular…

A: P- Bonding in ligand group orbital- we will discuss p-bonding in ligand by taking some eexamples-…

Q: d. Fig. 10.41 The occupation of energy levels in a d'octahedral complex.

Q: Which orbital is LUMO in the molecular orbital diagram drawn for the sigma interaction of the…

A: We can draw the molecular orbital diagram for the complex to answer the question. LUMO is the lowest…

Q: Which of the following orders is correct for Tolman cone angles for PR3 ligands? а. РМез > РET3 b.…

A: Tolman Cone angle → Depends on the basis of steric size . Layer the size layer is the…

Q: By using valence bond theory and ligand field theory, prove that [Ru(OMe)2(PMe3)4] is a paramagnetic…

Q: If the complex [W(C5H5)2(CO)2] follows the 18e rule, what is the hapticity of each (C5H5)? a. 5 and…

A: Hepticity explains the number of atoms from a ligand coordinate with central metal. Here, Tungsten…

Q: F3C-M ligand is a pi acceptor/ pi donor or neither?

A: pi acceptor ligands are those in which it have empty p orbitals and a good sigma donor. When bonding…

Q: CI Ph2(Et)P-Pt-P(Et)Ph2 EtP-Pt-PEt3 MegP-Pt-CI ČI 242 pm ČI 229 pm CI 237 pm Q.3 For the first…

A: Electronic effect: It influence the structure of molecule, reactivity of molecule, or properties of…

Q: The number of spin-allowed ligand field transitions for Ni(II) complexes with A2g * :ground state…

A: The number of spin allowed ligand field transition for Ni(II) complex with 3A2g ground state are =…

Q: Using only sigma overlap parameters, a 5-coordinate dº complex TABLE 10.10 Angular Overlap…

A: In the given problem the preferential geometry of a 5-coordinated d6 complex is needed to determined…

Q: Jahn-Teller distortions are often encountered with а. octahedral complexes of dº and high o spin d4…

A: Jahn teller distortion occurs in those complexes which has unpaired electron in t2g or eg orbital ie…

Q: OUEST. 2. There has been three bands (264 nm, 408 nm and 575 nm) observed in the UV-Vis spectrum of…

A: Crystal field stabilization energy(CFSE ): Depending on the particular ligand field geometry and…

Q: Please help with this work. Derive the free-ion term (show the steps) and (b) find (ONLY) the ground…

A: This is multi part questions and as per answering guidelines I can only answer first 3 questions if…

Q: A first row transition metal ion, M³+, was allowed to react with two sets of monodentate ligands, D…

A: Similar to the domains in ferromagnetic materials, unpaired electrons in paramagnetic compounds…

Q: Rank the following complexes from smallest to largest d-orbital splitting i) [Fe(CN)6]³- ii)…

A: The d-orbital splitting energy can be calculated by the following relation: Splitting…

Q: A complex of metal M"+ has the following electronic distribution ind orbitals, 1l E The neutral M…

Q: An octahedral complex, MA,B2C2 (A, B, C are all monodentate ligands), has a total of 6…

A: The correct option is as follows:

Q: Answer the following questions for square planar metal complexes ML4 (point group D4h): 2) draw the…

A: The square planar complexes belong to the D4h group which shows a complex MO diagram due to the fact…

Q: A complex of formula [M(N = CCH3)6](NO3)2, in which the M(II) ion is that of a firstrow (3d)…

A: Answer: With the help of Magnetic moment, find out the number of unpaired electrons central metal…

Q: Characterize each of t Following CooXDivation comprends M₂₂ [Cr CH₂)₂ (CN)+] [M(NH3)3 Brolls…

Q: Determine the number of stereoisomers for square-planar metal complex: [PtCl2(en)]? en…

Q: 5.2.1. = (Kn)(Kn). If he was found to be 2.314 x 10³ dm³ mol, which of the two ligands, H₂0 and NHs,…

Q: For [Fe(CN)6]*, please write the valence electron configuration of the metal ion, the ground- state…

A: In the given complex, iron is the central metal atom which is present in +2 oxidation state. The…

Q: What is the LFSE for the [Co(bipy)3]Cl2 complex, knowing that $\Delta$o = 11300 cm-1 and P= 22500…

A: LFSE is the ligand field stabilization energy. For the given complex, Co is in +2 state. A strong…

Q: QUESTION 1. The complex [Ni(salicylaldato)2(H₂O)2] can be prepared by reacting two equivalents of…

Q: The ligand-field-stabilization-energies (LFSE) of three pairs of [ML«]³" and [ML«J* complexes are…

A: For octahedral complexes: For a high spin complex the energy gap between t2g and eg is less but for…

Q: Magnetic moment of a first-row transition-metal complex M (H,O), is 3.9 Bohr magnetons. Identify the…

Q: A first-row transition-metal complex of formula [M(H2O)6]²+ has a magnetic moment of 3.9 Bohr mag-…

A: Given: Magnetic moment = 3.9 B.M Complex is MH2O62+, here M is first-row transition metal

Q: Three absorption bands were observed at 11200, 18350, 29000 cm-1 in the electronic spectrum of the…

Q: Jhane Teller distortions for Co(II) octahedral LS and HS complexes?

Q: P15A.8* D. Sellmann et al. (Inorg. Chem. 36, 1397 (1997)) describe the synthesis and reactivity of…

Q: The correct systematic name for the complex [Mn(NCS)3(OH₂) (Ox)] is O tris(thiocyanato-KN)…

A: k is used to specify which ligand atoms are bonding to the central atom. Oxidation state of Mn in…

Q: 1- The gap between the higher and lower energy levels is called (CFSE). 2- Splitting of d orbitals…

A: As per the rules, only the first three sub-parts of a question can be answered: Co-ordination…

Q: Determine the d orbital splitting of [FeCl4]-complex. A) (e)0(t2)5 B) (t2)3(e)2 C) (t2)5(e)0 D)…

Q: Characterize each of the Fallowing COORDINation comprend's M₂ [Cr CH₂)₂ (CN)+] [M(NH3)3 Brg [M₂…

A: Given that, some metal complexes are Mg[Cr(H2O)4(CN)4] [Ni(NH3)3Br5]Cl3 [Mn(H2O)2(C2O4)2] We have…

Q: i, d electron configuration ii crystal field theory summary i high/low-spin assignment based on…

A: (i)d electron configuration Electronic configuration = (n-1)d1-10ns1-2 the element of d block have…

Q: (g (n' (h M(n-CSH5):(CO)(M=M bond) 3 Calculate the Total Valence Electron (TVE) and sketch the…

A: Total valence electrons of a complex is equals to the valence electron of metal (d + s electrons)…

Q: Calculate total spin moment (S) for the Mn complex. * +2.0 +2.5 +1.5 +1.0

Q: Answer the following questions for square planar metal complexes ML4 (point group Dan): 2) draw the…

A: Electronic configuration of pt78 = [Xe]6s24f145d8

Q: 1. Using the MO scheme provided below, calculate the bond order for the ligand-metal bonds in a ML6…

A: Electron configuration of Co: [Ar] 3d7 4s2 Electron configuration of Co2+: [Ar]3d7 There are 6 NH3…

Q: OUEST. 2. There has been three bands (264 nm, 408 nm and 575 nm) observed in the UV-Vis spectrum of…

A: The complex can be written asCrH2O63+ The electronic configuration of chromium…

Q: prove that [Ru(OMe)2(PMe3)4] is a paramagnetic high spin octahedral complex using valence bond…

A: According to valancy bond theory we can say that about the hybridisation of the complexes.…

Q: . Co(NH3)63+ is a low-spin complex while CoF63- is a high-spin complex. Give a rational for this…

A: A question based on coordination chemistry, which is to be accomplished.

Concept explainers

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.

Question

For this species below, state the point group
НО
ОН
For this species below, state the point group
2-
OH2
.CI
CI
Mn
'CI
ÓH2
CI
Which of the following ligands would be best for chelating a Cu(II) ion?
HS
SH
H2N
ОН
НО
Но

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Chelation

VIEW

Solution

VIEW

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

By using the given 1) electronic absorption spectrum, 2) the Tanabo-Sugano diagram for d3 complex in octahedral ligand field and 3) the absorption/emission spectra, explain the following: a) Ligand field states (to support your explanation show the filling of the orbitals) b) Radiative transitions (to support your explanation refer to fluorescence, phosphorescence and Stokes’ shift)
Sketch structure of Mo(DMe) Cl2 (NMe,)2 , thhen apply ean to this complex showing ligand analysis and oxidation state analysis
What is the name of the following coordination complexes and state their point groups. (Justify your answer)
Determine the symmetry of the orbital groups for the donor sigma bonds (σ) of the ligand in an octahedral complex. Construct an MO diagram for the formation of this complex and indicate which orbitals determine the Δo. Clearly indicate the procedure.
Construct an MO correlation diagram for the complex ion[Ni(NH3)6]2+ and populate the orbitals with electrons. Do youexpect p bonding to be important for this complex? Whatfeatures of this diagram correspond to those predicted usingcrystal field theory? What kind of bonding would VB theorypredict for d8 complexes, and how does MO theory accountfor the bonding more accurately, even qualitatively?
(a) What coordination geometries could [AuI4]− take and how might it differ from the [AuCl4]− ion? (b) Which of Ag(NO3) and Ag2S would be expected to be more effective at removing bromide, Br−, from solution? Explain your reasoning.
When Alfred Werner was developing the field of coordinationchemistry, it was argued by some that the opticalactivity he observed in the chiral complexes he hadprepared was due to the presence of carbon atoms in themolecule. To disprove this argument, Werner synthesizeda chiral complex of cobalt that had no carbon atoms in it,and he was able to resolve it into its enantiomers. Design acobalt(III) complex that would be chiral if it could be synthesizedand that contains no carbon atoms. (It may not bepossible to synthesize the complex you design, but we willnot worry about that for now.)
It is observed that the substitution reactions of square plane complexes generally follow the SN2 mechanism. Is that true or false?
Describe main features of the evidence of M-CºC characterization and corresponding techniques of this complex (COCL(PPh3)2-III(CF3)2)...?
The ligand thiocyanate (SCN-) is ambidentate. Which of the following metals will it most likely interact via the sulfur atom? Circle the letter for your choice and write a brief and clear justification fro your answer. a) Tl+ b) Pb2+ c) Cu2+ d) Fe3+ e) Zr4+
Draw the SALC set for the ferrocene ligand set, describing in detail the steps used. Which isomer are you considering?
CFT is applicable to molecules in geometries other than octahedral. In octahedral complexes, remember that the lobes of the eg set point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place,but now we have only four ligands located between the axes (as given). None of the orbitals points directly at the tetrahedral ligands. However, the eg set (along the Cartesian axes) overlaps with the ligands less than does the t2g set. By analogy with the octahedral case, predict the energy diagram for the d orbitals in a tetrahedral crystal field. To avoid confusion, the octahedral eg set becomes a tetrahedral e set, and the octahedral t2g set becomes a t2 set.