which of the following has the greatest No. of unpaired electron? Select one: а. [Mn(CN)2- b. [Co(en) ]+ C. С. [CUCL]2- d. FECL3-

Q: प्रश्न 1 एवं 2 के लिये अनुच्छेद The isomerism which is due to change in position of linking atoms in…

A: Let us discuss the question step by step.

Q: Is bis(oxalato)platinate(II) a diamagnetic square planar complex? Yes or no? How about at the start…

A:

Q: (b) What are the effects of r-donor and t-acceptor ligands on the splitting of metal d orbitals in…

A: Answer- When the ligands approach the central metal ion, d- or f-subshell degeneracy is broken due…

Q: Indicate the coordination number and the oxidation num- ber of the metal for each of the following…

A: The oxidation of central metal atoms of given coordination compounds are calculated as,

Q: The formations of [cis-PtCh(NH3)2] and [trans-PtCl½(NH3)2] are different although same ligands are…

A: The formation of above complex cab be explain by trans effect . the trans effect is the effect that…

Q: 1.43g sample of the complex [Co(NH3)4CO3]NO3 (MM=249 g/mol) was ignited in a crucible to convert all…

A: Previded amount of sample [Co(NH3)4CO3]NO3=1.43g Molar mass of [Co(NH3)4CO3]NO3=249g/mol Provided…

Q: Which of these ligands can participate in linkage isomerism:(a) SCN-; (b) S2O32-(thiosulfate); (c)…

A: Ligands having 2 donor atoms and which are capable of ligating through any of these donor atoms at a…

Q: Which one of the following statements is FALSE? O In an octahedral crystal field, the d electrons on…

A: so we will determine the false statement of this question.

Q: Which ligand below gives the LEAST stability to Pd2+ in forming a square planar complex? О а. NH3 O…

A: a) NH3 will form the least stable complex.  Because we know that more is the basicity of lignad more…

Q: ) Figure 5 shows four energy diagrams, labelled A to D. The diagrams depict possible configurations…

A:

Q: C.Draw the molecular orbital diagram for B2 and find the bond order? D.The geometry of [Ni(CN)4]2-…

A:

Q: When the valenced orbitals of the central metal ion are split in energy in an octahedral ligand…

A: d- orbital consists of 5 orbitals that are- dxy ,dyz , dxz ,dz2 and dx2-y2

Q: a) Give an explaination on the stabilities of [V(CO)6J, [Ni(CO)4] and [Mn(CO)s] complexes. [Mn(CO)s]…

A: Introduction :  We have to tell stability of these complexes .

Q: Which first-row transition metal(s) has the following highest possible oxidation state?a. +3 b. +7…

A: a) The first-row transition metals that have +3 as the highest possible oxidation state are as…

Q: Explain the following: (i) Nickel does not form low spin octahedral complexes. (ii) The Tt-complexes…

A: Nickel does not form low spin octahedral complexes. Because, the electronic configuration of Nickel…

Q: and eg t2g d. An analogous compound, [Cu(H₂O)6]2+ has a different arrangement of the Draw the…

A: Given that, a metal complex is [Cu(H2O)6]2+. We have to tell the different arrangement of the…

Q: Among the complex ions formed by M³* (M is a transition metal in 3d block) are the following:…

A: From given  Each of the given complexes is correctly matched with the respective colors.

Q: Which of the following statements is true?     Cis-trans and mer-fac isomers are examples of…

A: A coordination complex consists of a central metal atom that is surrounded by bounded molecules…

Q: Consider the coordination complex [Cr(OH2)3CI3]Br3 Identify the ligands by name (include the word…

A: Given complex--- [Cr(OH2)3Cl3]Br3

Q: 16 - When the ligands move along the x, y and z axes of d orbital in metal ion (octahedral…

A: A coordination complex is formed more electron rich species i.e. ligands approach the metal ion and…

Q: How many unpaired electrons are there in a strong field iron(II) octahedral complex? 0 1 2 3

A: Since you have asked multiple type questions, we will solve only first  questions for you. If you…

Q: Explain the following :(i) Low spin octahedral complexes of nickel are not known.(ii) The…

A: Low spin octahedral complexes are formed when the central metal atom undergo d2sp3 hybridisation by…

Q: octahedral complex is found to absorb visible light, with the absorption maximum occurring at 507…

A: The absorption with maximum wavelength by an electron is equal to the energy difference between…

Q: The complexes of Fe^3+ have magnetic properties that depend onwhether the ligands are strong or weak…

A: The ligands are ranked on the basis of energy difference between the t2g and eg orbitals. When the…

Q: When we consider the reaction of Fe3+ ion (SCN) with its ligand, by showing the ion-ligand bond in…

A: The reaction between Fe3+ and SCN- could be given as, Fe3+aq+SCN-aq→FeSCN2+ SCN- is a thiocyanate…

Q: A d' octahedral complex is found to absorb visible light, with the absorption maximum occurring at…

A:

Q: For each of the following metals, write the electronic configurationof the atom and its 2+ ion: (a)…

A: Electronic Configuration is defined as the distribution of electrons of an atom or molecules in…

Q: The absorption spectrum of the complex ion [Rh(NH,)6+ has maximum absorbance at 295 nm. Calculate…

A: Given, Maximum absorbance of the ion  295 nm ∆ = hc/ λ = [( 6.626 x 10 -34 Js ) x ( 3 x 10 8 m/s) x…

Q: [FeL6]* complex (L indicates a monodentate ligand) has a magnetic m approximately 1.73 B.M. a) What…

A: The electronic configuration is given by, [FeL6]3- i.e. Fe 3+: 18(Ar) 4s0 3d5

Q: Why dp transition elements show variable oxidation states? In 3d series (Sc to Zn), which element…

A: Outer electronic configuration and Oxidation states  Sc  3d1 4s2                                + 2,…

Q: What's the ligand field of metallo-porphyrins?

A: Porphyrins are chemicals used to make hemoglobin. The structure of porphyrin consists of four…

Q: 1) In accordance to Crystal Field Theory (CFT): Explain in details the difference between [Fe(CN),]*…

A:

Q: For each of the following metals, write the electronic configurationof the atom and its 3+ ion: (a)…

A:

Q: Which of these ligands can participate in linkage isomerism:(a) NO2-; (b) SO2; (c) NO3-? Explain…

A: Linkage isomerism Suppose two complexes have the same molecular formula. But their structures differ…

Q: The values for lmax for complex A and B are 512 nm and 650 nm respectively.  A has the structure…

A: Given S.No. Complex  Imax 1 [Co(NH3)4CO3]NO3 512 nm 2 [Co(NH3)4Cl2]Cl.  650 nm Explain the…

Q: 3+ cation, the energies of the valence d orbitals on When a certain strong-field ligand forms an…

A:

Q: 1) Why are lanthanide  complexes always weak field in nature , second and third d-transition metal…

A: Hey, since there are multiple questions posted, we will answer first question. If you want any…

Q: 1) In accordance to Crystal Field Theory (CFT): Explain in details the difference between [Fe(CN),]…

A:

Q: Metal complex A appears blue (440 nm) and complex B appears red (670 nm). Which has a larger value…

A: When a metal complex appears blue, it absorbs the complementary color orange When a metal complex…

Q: a) Which is more likely to be paramagnetic, Fe(NO,), or Fe(0H), ? O Fe(OH),+ O Fe(NO2),+ 4- b) Why?…

A: a) in Fe(NO2)64- , unpaired electrons = 0 and in Fe(OH)64-, unpaired electrons = 4

Q: 10) What is a representative orbital-filling diagram for the cobalt ion in the low spin complex of…

A:

Q: Is a linkage isomer a type of constitutional isomer orstereoisomer? Explain

A: Linkage isomers are the coordination compounds with same metal and ligands but differ in the…

Q: The size of the crystal field splitting only influences the arrangement of electrons when there is a…

A: Crystal field theory- This theory was developed by John Hasbrouck van Vleck and Hans Bethe.…

Q: Consider the coordination compound [Ni(C₂O4)2(H₂O)2] Cl2 and identify ligands a. C₂04-2, CI- -2 O b.…

A:

Q: 1. Sketch all isomers of the following. Indicate clearly each pair of enantiomers. Multidentate…

A: 1. a) [Cr(bipy)(H2O)BrF]+: It is a coordination compound with four types of ligands attached to the…

Q: (b) Which copper complex ion is colourless? O A [CuCl] I B [CuClj²- O C [Cu(H,O),J** 2+ O D…

A: Cu+ ion has a d10 configuration and all eg orbitals are filled. There is no transition between the…

Q: The three complex ions [Mn(CN),]³-, [Mn(CN),J*¯, and [Mn(CN),]³- have all been synthesized and all…

A: All three complexes has cyanide ligand, CN- which is a strong field ligand , thus all complexes are…

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.